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A borate is any of a range of boron oxyanions, anions containing boron and oxygen, such as orthoborate BO 3− 3, metaborate BO − 2, or tetraborate B 4 O 2− 7; or any salt of such anions, such as sodium metaborate, Na + [BO 2] − and borax (Na +) 2 [B 4 O 7] 2−. The name also refers to esters of such anions, such as trimethyl borate B ...
The Borate Minerals are minerals which contain a borate anion group. The borate (BO 3) units may be polymerised similar to the SiO 4 unit of the silicate mineral class. This results in B 2 O 5, B 3 O 6, B 2 O 4 anions as well as more complex structures which include hydroxide or halogen anions. [2] The [B(O,OH) 4] − anion exists as well.
24. Non-hydrated borate; 25. Non-hydrated borate containing hydroxyl anion or halogens; 26. Hydrated borate containing hydroxyl anion or halogens; 27. Compound borate; Sulfates, chromates. and molybdates. 28. Acidic and normal non-hydrated sulfates; 29. Acid and normal hydrated sulfates; 30. Non-hydrated sulfates containing hydroxyl anion or ...
The [BAr F 4] − anion with four fluorinated aryl groups distributed tetrahedrally about a central boron atom. Tetrakis[3,5-bis(trifluoromethyl)phenyl]borate is an anion with chemical formula [{3,5-(CF 3) 2 C 6 H 3} 4 B] −, which is commonly abbreviated as [BAr F 4] −, indicating the presence of fluorinated aryl (Ar F) groups.
The orthoborate ion is known in the solid state, for example, in calcium orthoborate (Ca 2+) 3 ([BO 3] 3−) 2, [1] where it adopts a nearly trigonal planar structure. It is a structural analogue of the carbonate anion [CO 3] 2−, with which it is isoelectronic.
A metaborate is a borate anion consisting of boron and oxygen, with empirical formula BO − 2. Metaborate also refers to any salt or ester of such anion (e.g. salts such as sodium metaborate NaBO 2 or calcium metaborate Ca(BO 2) 2, and esters such as methyl metaborate CH 3 BO 2). Metaborate is one of the boron's oxyanions.
Borate nitrates are mixed anion compounds containing separate borate and nitrate anions. List. chem mw crystal system space group unit cell Å volume density
Unlike silicates, boron minerals never contain boron with coordination number greater than four. A typical motif is exemplified by the tetraborate anions of the common mineral borax, shown at left. The formal negative charge of the tetrahedral borate center is balanced by metal cations in the minerals, such as the sodium (Na +) in borax. [1]