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The driving force shown here as ' ' is expressed in units of moles per unit of volume, but in some cases the driving force is represented by other measures of concentration with different units. For example, the driving force may be partial pressures when dealing with mass transfer in a gas phase and thus use units of pressure.
In physical chemistry, the Evans–Polanyi principle (also referred to as the Bell–Evans–Polanyi principle, Brønsted–Evans–Polanyi principle, or Evans–Polanyi–Semenov principle) observes that the difference in activation energy between two reactions of the same family is proportional to the difference of their enthalpy of reaction.
There are some notable similarities in equations for momentum, energy, and mass transfer [7] which can all be transported by diffusion, as illustrated by the following examples: Mass: the spreading and dissipation of odors in air is an example of mass diffusion. Energy: the conduction of heat in a solid material is an example of heat diffusion.
We can consider as an example a positively charged ion, such as K +, and a negatively charged membrane, as it is commonly the case in most organisms. [4] [5] The membrane voltage opposes the flow of the potassium ions out of the cell and the ions can leave the interior of the cell only if they have sufficient thermal energy to overcome the energy barrier produced by the negative membrane ...
The adsorption of larger biomolecules such as proteins is of high physiological relevance, and as such they adsorb with different mechanisms than their molecular or atomic analogs. Some of the major driving forces behind protein adsorption include: surface energy, intermolecular forces, hydrophobicity, and ionic or electrostatic interaction. By ...
In mass spectrometry, fragmentation is the dissociation of energetically unstable molecular ions formed from passing the molecules mass spectrum.These reactions are well documented over the decades and fragmentation patterns are useful to determine the molar weight and structural information of unknown molecules.
The driving forces for such reaction is the electron donating abilities of the radical sites: N > S, O,π > Cl, Br > H. [11] An example is the cleavage of carbon-carbon bonds next to a heteroatom. In this depiction, single-electron movements are indicated by a single-headed arrow .