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Sodium carbonate is used in the production of sherbet powder. The cooling and fizzing sensation results from the endothermic reaction between sodium carbonate and a weak acid, commonly citric acid, releasing carbon dioxide gas, which occurs when the sherbet is moistened by saliva.
The ammonia from reaction (III) is recycled back to the initial brine solution of reaction (I). The sodium bicarbonate (NaHCO 3) precipitate from reaction (I) is then converted to the final product, sodium carbonate (washing soda: Na 2 CO 3), by calcination (160–230 °C), producing water and carbon dioxide as byproducts:
A key step in this process is the reduction of sodium sulfate with coal: [3] Na 2 SO 4 + 2 C → Na 2 S + 2 CO 2. The Na 2 S is then treated with calcium carbonate to give sodium carbonate, a commodity chemical. Recently, development of the 'MagSonic' carbothermic magnesium process has restarted interest in its chemistry: [4] MgO + C ↔ Mg + CO
This conversion entails two parts. First is the carbothermic reaction whereby the coal, a source of carbon, reduces the sulfate to sulfide: Na 2 SO 4 + 2 C → Na 2 S + 2 CO 2. In the second stage, is the reaction to produce sodium carbonate and calcium sulfide. This mixture is called black ash. [citation needed] Na 2 S + CaCO 3 → Na 2 CO 3 + CaS
or, the reaction of sodium carbonate with portlandite, also important for the catalysis of the alkali–carbonate reaction as emphasized by Fournier and Bérubé (2000) and Bérubé et al. (2005): [17] [18] Na 2 CO 3 + Ca(OH) 2 → CaCO 3 + 2 NaOH
It is a product of the Solvay process used to produce sodium carbonate: [3] CO 2 + 2 NH 3 + 2 NaCl + H 2 O → 2 NH 4 Cl + Na 2 CO 3. Not only is that method the principal one for the manufacture of ammonium chloride, but also it is used to minimize ammonia release in some industrial operations.
The net reaction between an aldehyde (or an alpha-hydroxy-ketone) and the copper(II) ions in Benedict's solution may be written as: RCHO + 2 Cu 2+ + 5 OH − → RCOO − + Cu 2 O + 3 H 2 O. The hydroxide ions in the equation forms when sodium carbonate dissolves in water. With the citrate included, the reaction becomes:
The alkali–carbonate reaction is an alteration process first suspected in the 1950s in Canada for the degradation of concrete containing dolomite aggregates. [1] [2]Alkali from the cement might react with the dolomite crystals present in the aggregate inducing the production of brucite, (MgOH) 2, and calcite (CaCO 3).