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Borate ions occur, alone or with other anions, in many borate and borosilicate minerals such as borax, boracite, ulexite (boronatrocalcite) and colemanite. Borates also occur in seawater, where they make an important contribution to the absorption of low frequency sound in seawater. [1] Borates also occur in plants, including almost all fruits. [2]
The Borate Minerals are minerals which contain a borate anion group. The borate (BO 3) units may be polymerised similar to the SiO 4 unit of the silicate mineral class. This results in B 2 O 5, B 3 O 6, B 2 O 4 anions as well as more complex structures which include hydroxide or halogen anions. [2] The [B(O,OH) 4] − anion exists as well.
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The formal negative charge of the tetrahedral borate center is balanced by metal cations in the minerals, such as the sodium (Na +) in borax. [1] The tourmaline group of borate-silicates is also a very important boron-bearing mineral group, and a number of borosilicates are also known to exist naturally.
Media in category "Borate minerals" This category contains only the following file. Watermelon Tourmaline.JPG 2,560 × 1,920; 2.3 MB
Borax (also referred to as sodium borate, tincal (/ ˈ t ɪ ŋ k əl /) and tincar (/ ˈ t ɪ ŋ k ər /)) is a salt (ionic compound), a hydrated or anhydrous borate of sodium, with the chemical formula Na 2 H 20 B 4 O 17. [1] [a] It is a colorless crystalline solid that dissolves in water to make a basic solution.
Zinc borate refers to a family of inorganic compounds consisting of borate of zinc.They are white solids with the formulas 4ZnO·B 2 O 3 ·H 2 O, ZnO·B 2 O 3 ·1.12H 2 O, ZnO·B 2 O 3 ·∼2H 2 O, 6ZnO·5B 2 O 3 ·3H 2 O, 2ZnO·3B 2 O 3 ·7H 2 O, 2ZnO·3B 2 O 3 ·3H 2 O, 3ZnO·5B 2 O 3 ·14H 2 O, and ZnO·5B 2 O 3 ·4.5H 2 O.
The orthoborate ion is known in the solid state, for example, in calcium orthoborate (Ca 2+) 3 ([BO 3] 3−) 2, [1] where it adopts a nearly trigonal planar structure. It is a structural analogue of the carbonate anion [CO 3] 2−, with which it is isoelectronic.