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Many metal and nonmetal sulfides, e.g. aluminium sulfide, phosphorus pentasulfide, silicon disulfide liberate hydrogen sulfide upon exposure to water: [28] 6 H 2 O + Al 2 S 3 → 3 H 2 S + 2 Al(OH) 3. This gas is also produced by heating sulfur with solid organic compounds and by reducing sulfurated organic compounds with hydrogen.
Hydrogen sulfide is most commonly inhaled, though through prolonged exposure skin and eye irritations resulting in painful dermatitis and burning eyes can occur. [10] Symptoms of acute exposure include nausea, headaches, disturbed equilibrium, tremors, convulsions and skin and eye irritations. [10]
Hydrogen sulfide is also a potent cellular toxin, blocking the cytochrome system and inhibiting cellular respiration. More water-soluble gases (e.g. chlorine, ammonia, sulfur dioxide, hydrogen chloride) dissolve in the upper airway and immediately cause mucous membrane irritation, which may alert people to the need to escape the exposure.
Prolonged low-level exposure may cause fatigue, pneumonia, loss of appetite, headaches, irritability, poor memory, and dizziness. High concentrations of hydrogen sulfide (>150 ppm) can produce olfactory fatigue, whereby the scent becomes undetectable. At higher concentrations (>300 ppm), hydrogen sulfide can cause loss of consciousness and death.
One of these chemical reactions involves hydrogen sulfide (H 2 S) in sulfide stress cracking (SSC), a significant problem for the oil and gas industries. [32] After a manufacturing process or treatment which may cause hydrogen ingress, the component should be baked to remove or immobilize the hydrogen. [29]
Amine gas plant at a natural gas field. Amine gas treating, also known as amine scrubbing, gas sweetening and acid gas removal, refers to a group of processes that use aqueous solutions of various alkylamines (commonly referred to simply as amines) to remove hydrogen sulfide (H 2 S) and carbon dioxide (CO 2) from gases.
Exposure of the eyes and skin tends to be corrosive, causing blurred vision and severe deep burns. Inhalation of these agents causes burning of the throat, coughing, vomiting, headache, pain in chest, tightness in chest, and respiratory and circulatory failure. Examples of pulmonary agents include: Chlorine gas; Chloropicrin (PS) Diphosgene (DP)
Sulfur medications such as phenacetin, metoclopramide, dapsone, phenzopyridine, and trimethoprim-sulfamethoxazole; hydrogen-sulfide-producing intestinal bacteria, such as Morganella morganii: Risk factors: Pulmonary arteriovenous malformation: Prevention: Avoidance of sulfur-containing compounds including drugs: Treatment: Blood transfusions