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The effective atomic number Z eff, (sometimes referred to as the effective nuclear charge) of an electron in a multi-electron atom is the number of protons that this electron effectively 'sees' due to screening by inner-shell electrons. It is a measure of the electrostatic interaction between the negatively charged electrons and positively ...
An example provided in Slater's original paper is for the iron atom which has nuclear charge 26 and electronic configuration 1s 2 2s 2 2p 6 3s 2 3p 6 3d 6 4s 2.The screening constant, and subsequently the shielded (or effective) nuclear charge for each electron is deduced as: [1]
On the most basic level, electronegativity is determined by factors like the nuclear charge (the more protons an atom has, the more "pull" it will have on electrons) and the number and location of other electrons in the atomic shells (the more electrons an atom has, the farther from the nucleus the valence electrons will be, and as a result ...
However, electrons of multi-electron atoms do not experience the entire nuclear charge due to shielding effects from the other electrons. In this case, the nuclear charge of atoms that experience this shielding is referred to as effective nuclear charge. Shielding increases as the number of an atom's inner shells increases. So from left-to ...
As the nuclear charge of the nucleus increases across the period, the electrostatic attraction increases between electrons and protons, hence the atomic radius decreases, and the electron cloud comes closer to the nucleus [10] because the electrons, especially the outermost one, are held more tightly by the higher effective nuclear charge.
The shielding effect can be defined as a reduction in the effective nuclear charge on the electron cloud, due to a difference in the attraction forces on the electrons in the atom. It is a special case of electric-field screening. This effect also has some significance in many projects in material sciences.
Effective atomic number, denoted by Z eff, may refer to: Effective nuclear charge of an individual atom, as felt by electrons within that atom Effective atomic number (compounds and mixtures) of a composite material
The effective atomic number for electron interactions may be calculated with a similar approach. [5] [6] The cross-section based approach for determining Z eff is obviously much more complicated than the simple power-law approach described above, and this is why freely-available software has been developed for such calculations. [7]