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Infobox references. In chemistry, a superoxide is a compound that contains the superoxide ion, which has the chemical formula O− 2. [1] The systematic name of the anion is dioxide (1−). The reactive oxygen ion superoxide is particularly important as the product of the one-electron reduction of dioxygen O2, which occurs widely in nature. [2]
Bond order. In chemistry, bond order is a formal measure of the multiplicity of a covalent bond between two atoms. As introduced by Linus Pauling, bond order is defined as the difference between the numbers of electron pairs in bonding and antibonding molecular orbitals. Bond order gives a rough indication of the stability of a bond.
The bond-order formula at the bottom is closest to the reality of four equivalent oxygens each having a total bond order of 2. That total includes the bond of order 1 / 2 to the implied cation and follows the 8 − N rule [5] requiring that the main-group atom's bond-order total equals 8 − N valence electrons of the neutral atom ...
The σ from the 2p is more non-bonding due to mixing, and same with the 2s σ. This also causes a large jump in energy in the 2p σ* orbital. The bond order of diatomic nitrogen is three, and it is a diamagnetic molecule. [12] The bond order for dinitrogen (1σ g 2 1σ u 2 2σ g 2 2σ u 2 1π u 4 3σ g 2) is three because two electrons are now ...
The dioxygenyl ion, O+. 2, is a rarely-encountered oxycation in which both oxygen atoms have a formal oxidation state of + 1 2 . It is formally derived from oxygen by the removal of an electron: O 2 → O+. 2 + e −. The energy change for this process is called the ionization energy of the oxygen molecule.
Oxygen is a chemical element; it has symbol O and atomic number 8. It is a member of the chalcogen group in the periodic table, a highly reactive nonmetal, and an oxidizing agent that readily forms oxides with most elements as well as with other compounds. Oxygen is the most abundant element in Earth's crust, and after hydrogen and helium, it ...
Oxygen compounds. Water (H 2 O) is the most familiar oxygen compound. The oxidation state of oxygen is −2 in almost all known compounds of oxygen. The oxidation state −1 is found in a few compounds such as peroxides. Compounds containing oxygen in other oxidation states are very uncommon: − 1⁄2 (superoxides), − 1⁄3 (ozonides), 0 ...
Carbon–oxygen bond. A carbon–oxygen bond is a polar covalent bond between atoms of carbon and oxygen. [1][2][3]: 16–22 Carbon–oxygen bonds are found in many inorganic compounds such as carbon oxides and oxohalides, carbonates and metal carbonyls, [4] and in organic compounds such as alcohols, ethers, and carbonyl compounds. [5]: 32–36 ...