Search results
Results From The WOW.Com Content Network
In physical chemistry, the Arrhenius equation is a formula for the temperature dependence of reaction rates.The equation was proposed by Svante Arrhenius in 1889, based on the work of Dutch chemist Jacobus Henricus van 't Hoff who had noted in 1884 that the van 't Hoff equation for the temperature dependence of equilibrium constants suggests such a formula for the rates of both forward and ...
Temperature dependence of viscosity. Viscosity depends strongly on temperature. In liquids it usually decreases with increasing temperature, whereas, in most gases, viscosity increases with increasing temperature. This article discusses several models of this dependence, ranging from rigorous first-principles calculations for monatomic gases ...
This model can be applied to soft solids: thermoplastic polymers in the vicinity of their melting temperature, fresh concrete (neglecting its aging), and numerous metals at a temperature close to their melting point. The equation introduced here, however, lacks a consistent derivation from more microscopic model and is not observer independent.
Boyle's law is a gas law, stating that the pressure and volume of a gas have an inverse relationship. If volume increases, then pressure decreases and vice versa, when the temperature is held constant. Therefore, when the volume is halved, the pressure is doubled; and if the volume is doubled, the pressure is halved.
(Note - the relation between pressure, volume, temperature, and particle number which is commonly called "the equation of state" is just one of many possible equations of state.) If we know all k+2 of the above equations of state, we may reconstitute the fundamental equation and recover all thermodynamic properties of the system.
Kinetic theory of gases. The temperature of the ideal gas is proportional to the average kinetic energy of its particles. The size of helium atoms relative to their spacing is shown to scale under 1,950 atmospheres of pressure. The atoms have an average speed relative to their size slowed down here two trillion fold from that at room temperature.
Newton's law of cooling. In the study of heat transfer, Newton's law of cooling is a physical law which states that the rate of heat loss of a body is directly proportional to the difference in the temperatures between the body and its environment. The law is frequently qualified to include the condition that the temperature difference is small ...
Clausius–Clapeyron relation. The Clausius–Clapeyron relation, in chemical thermodynamics, specifies the temperature dependence of pressure, most importantly vapor pressure, at a discontinuous phase transition between two phases of matter of a single constituent. It is named after Rudolf Clausius [1] and Benoît Paul Émile Clapeyron. [2]