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  2. Bromocyclopentane - Wikipedia

    en.wikipedia.org/wiki/Bromocyclopentane

    Bromocyclopentane is a derivative of cyclopentane, an alkyl halide with the chemical formula C 5 H 9 Br. It is a colorless to light yellow liquid at standard temperature and pressure . Uses

  3. SN1 reaction - Wikipedia

    en.wikipedia.org/wiki/SN1_reaction

    An example of a reaction taking place with an S N 1 reaction mechanism is the hydrolysis of tert-butyl bromide forming tert-butanol: This S N 1 reaction takes place in three steps: Formation of a tert-butyl carbocation by separation of a leaving group (a bromide anion) from the carbon atom: this step is slow. [5] Recombination of carbocation ...

  4. SN2 reaction - Wikipedia

    en.wikipedia.org/wiki/SN2_reaction

    Competition experiment between SN2 and E2. With ethyl bromide, the reaction product is predominantly the substitution product. As steric hindrance around the electrophilic center increases, as with isobutyl bromide, substitution is disfavored and elimination is the predominant reaction. Other factors favoring elimination are the strength of the ...

  5. Nucleophilic aromatic substitution - Wikipedia

    en.wikipedia.org/wiki/Nucleophilic_aromatic...

    In the compound methyl 3-nitropyridine-4-carboxylate, the meta nitro group is actually displaced by fluorine with cesium fluoride in DMSO at 120 °C. [7] Nucleophilic aromatic substitution at pyridine. Although the Sandmeyer reaction of diazonium salts and halides is formally a nucleophilic substitution, the reaction mechanism is in fact ...

  6. Associative substitution - Wikipedia

    en.wikipedia.org/wiki/Associative_substitution

    Associative substitution describes a pathway by which compounds interchange ligands. The terminology is typically applied to organometallic and coordination complexes, but resembles the Sn2 mechanism in organic chemistry. The opposite pathway is dissociative substitution, being analogous to the Sn1 pathway. Intermediate pathways exist between ...

  7. SNi - Wikipedia

    en.wikipedia.org/wiki/SNi

    Some examples for this reaction were reported by Edward S. Lewis and Charles E. Boozer in 1952. [2] Mechanistic and kinetic studies were reported few years later by various researchers. [3] [4] Thionyl chloride first reacts with the alcohol to form an alkyl chloro sulfite, actually forming an intimate ion pair.

  8. Substitution reaction - Wikipedia

    en.wikipedia.org/wiki/Substitution_reaction

    Coupling reactions are a class of metal-catalyzed reactions involving an organometallic compound RM and an organic halide R′X that together react to form a compound of the type R-R′ with formation of a new carbon–carbon bond. Examples include the Heck reaction, Ullmann reaction, and Wurtz–Fittig reaction. Many variations exist. [3]

  9. Glossary of chemical formulae - Wikipedia

    en.wikipedia.org/wiki/Glossary_of_chemical_formulae

    Chemical formula Synonyms CAS number CAgO carbonylsilver: CCl 2 F 2: dichlorodifluoromethane freon-12: 75-71-8 CCl 4: carbon tetrachloride tetrachloromethane: 56-23-5 C(CN) 4: tetracyanomethane: 24331-09-7 CFCl 3: trichlorofluoromethane freon-11: 75-69-4 CFCl 2 CF 2 Cl: chlorotrifluoromethane freon-13: 75-72-9 CHCl 3: chloroform ...