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For most substances, the solid–liquid phase boundary (or fusion curve) in the phase diagram has a positive slope so that the melting point increases with pressure. This is true whenever the solid phase is denser than the liquid phase. [ 6 ]
The composition range within which the primary phase remains constant is known as primary crystalline phase field. The liquidus temperature is important in the glass industry because crystallization can cause severe problems during the glass melting and forming processes, and it also may lead to product failure. [12]
A phase diagram for a fictitious binary chemical mixture (with the two components denoted by A and B) used to depict the eutectic composition, temperature, and point. ( L denotes the liquid state.) A eutectic system or eutectic mixture ( / j uː ˈ t ɛ k t ɪ k / yoo- TEK -tik ) [ 1 ] is a type of a homogeneous mixture that has a melting point ...
In the phase diagram, we can notice that the top point D of the phase diagram is the congruent melting point of the compound AB because the solid and liquid phases now have the same composition. Evidently, at this temperature , the two-component system has become a one-component system because both solid and liquid phases contains only the ...
The melting point of ordinary ice decreases with pressure, as shown by the phase diagram's dashed green line. Just below the triple point, compression at a constant temperature transforms water vapor first to solid and then to liquid. Historically, during the Mariner 9 mission to Mars, the triple point pressure of water was used to define "sea ...
The liquid–liquid critical point of a solution, which occurs at the critical solution temperature, occurs at the limit of the two-phase region of the phase diagram. In other words, it is the point at which an infinitesimal change in some thermodynamic variable (such as temperature or pressure) leads to separation of the mixture into two ...
This unusual feature of water is related to ice having a lower density than liquid water. Increasing the pressure drives the water into the higher density phase, which causes melting. Another interesting though not unusual feature of the phase diagram is the point where the solid–liquid phase line meets the liquid–gas phase line.
Phase transitions commonly refer to when a substance transforms between one of the four states of matter to another. At the phase transition point for a substance, for instance the boiling point, the two phases involved - liquid and vapor, have identical free energies and therefore are equally likely to exist.