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Nucleophilic aromatic substitution. A nucleophilic aromatic substitution (SNAr) is a substitution reaction in organic chemistry in which the nucleophile displaces a good leaving group, such as a halide, on an aromatic ring. Aromatic rings are usually nucleophilic, but some aromatic compounds do undergo nucleophilic substitution.
Bimolecular nucleophilic substitution (SN2) is a type of reaction mechanism that is common in organic chemistry. In the S N 2 reaction, a strong nucleophile forms a new bond to an sp 3 -hybridised carbon atom via a backside attack, all while the leaving group detaches from the reaction center in a concerted (i.e. simultaneous) fashion.
In chemistry, a nucleophilic substitution (SN) is a class of chemical reactions in which an electron -rich chemical species (known as a nucleophile) replaces a functional group within another electron-deficient molecule (known as the electrophile). The molecule that contains the electrophile and the leaving functional group is called the ...
For example, the substituent may determine the mechanism to be an SN1 type reaction over a SN2 type reaction, in which case the resulting Hammett plot will indicate a rate acceleration due to an EDG, thus elucidating the mechanism of the reaction. Another deviation from the regular Hammett equation is explained by the charge of nucleophile.
The unimolecular nucleophilic substitution (SN1) reaction is a substitution reaction in organic chemistry. The Hughes-Ingold symbol of the mechanism expresses two properties—"S N " stands for "nucleophilic substitution", and the "1" says that the rate-determining step is unimolecular. [1][2] Thus, the rate equation is often shown as having ...
Allylic rearrangement. An allylic rearrangement or allylic shift is an organic chemical reaction in which reaction at a center vicinal to a double bond causes the double bond to shift to an adjacent pair of atoms: It is encountered in both nucleophilic and electrophilic substitution, although it is usually suppressed relative to non-allylic ...
A substitution reaction (also known as single displacement reaction or single substitution reaction) is a chemical reaction during which one functional group in a chemical compound is replaced by another functional group. [1] Substitution reactions are of prime importance in organic chemistry. Substitution reactions in organic chemistry are ...
In chemistry, bond energy (BE) is one measure of the strength of a chemical bond. It is sometimes called the mean bond, bond enthalpy, average bond enthalpy, or bond strength. [1][2][3] IUPAC defines bond energy as the average value of the gas-phase bond-dissociation energy (usually at a temperature of 298.15 K) for all bonds of the same type ...