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Copper(II) sulfate is an inorganic compound with the chemical formula Cu SO 4.It forms hydrates CuSO 4 ·nH 2 O, where n can range from 1 to 7. The pentahydrate (n = 5), a bright blue crystal, is the most commonly encountered hydrate of copper(II) sulfate, [10] while its anhydrous form is white. [11]
During a water bath, which is usually 4–10 minutes, the solution should progress through the colors of blue (with no reducing sugar present), orange, yellow, green, red, and then brick red precipitate or brown (if a high concentration of reducing sugar is present). A color change would signify the presence of a reducing sugar.
Specifically, using Benedict's reagent and Fehling's solution the presence of the sugar is signaled by a color change from blue Cu(II) to reddish copper(I) oxide. [4] Schweizer's reagent and related complexes with ethylenediamine and other amines dissolve cellulose. [5] Amino acids such as cystine form very stable chelate complexes with copper(II).
Fehling's solution is prepared by combining two separate solutions: Fehling's A, which is a deep blue aqueous solution of copper(II) sulfate, and Fehling's B, which is a colorless solution of aqueous potassium sodium tartrate (also known as Rochelle salt) made strongly alkaline with sodium hydroxide. These two solutions, stable separately, are ...
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Cuprous sulfate is produced by the reaction of copper metal with sulfuric acid at 200 °C: [3]. 2 Cu + 2 H 2 SO 4 → Cu 2 SO 4 + SO 2 + 2 H 2 O. Cu 2 SO 4 can also be synthesized by the action of dimethyl sulfate on cuprous oxide: [4]
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