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  2. VSEPR theory - Wikipedia

    en.wikipedia.org/wiki/VSEPR_theory

    Valence shell electron pair repulsion (VSEPR) theory (/ ˈ v ɛ s p ər, v ə ˈ s ɛ p ər / VESP-ər, [1]: 410 və-SEP-ər [2]) is a model used in chemistry to predict the geometry of individual molecules from the number of electron pairs surrounding their central atoms. [3]

  3. Bent's rule - Wikipedia

    en.wikipedia.org/wiki/Bent's_rule

    According to VSEPR theory, diethyl ether, methanol, water and oxygen difluoride should all have a bond angle of 109.5 o. [12] Using VSEPR theory, all these molecules should have the same bond angle because they have the same "bent" shape. [12] Yet, clearly the bond angles between all these molecules deviate from their ideal geometries in ...

  4. Valence bond theory - Wikipedia

    en.wikipedia.org/wiki/Valence_bond_theory

    Semi-empirical quantum chemistry methods Møller–Plesset perturbation theory Configuration interaction Coupled cluster Multi-configurational self-consistent field Quantum chemistry composite methods Quantum Monte Carlo: Density functional theory; Time-dependent density functional theory Thomas–Fermi model Orbital-free density functional theory

  5. Molecular symmetry - Wikipedia

    en.wikipedia.org/wiki/Molecular_symmetry

    In chemistry, molecular symmetry describes the symmetry present in molecules and the classification of these molecules according to their symmetry. Molecular symmetry is a fundamental concept in chemistry, as it can be used to predict or explain many of a molecule's chemical properties , such as whether or not it has a dipole moment , as well ...

  6. Trigonal pyramidal molecular geometry - Wikipedia

    en.wikipedia.org/wiki/Trigonal_pyramidal...

    In organic chemistry, molecules which have a trigonal pyramidal geometry are sometimes described as sp 3 hybridized. The AXE method for VSEPR theory states that the classification is AX 3 E 1 . Phosphine , an example of a molecule with a trigonal pyramidal geometry.

  7. Linear molecular geometry - Wikipedia

    en.wikipedia.org/wiki/Linear_molecular_geometry

    As described by the VSEPR model, the five valence electron pairs on the central atom form a trigonal bipyramid in which the three lone pairs occupy the less crowded equatorial positions and the two bonded atoms occupy the two axial positions at the opposite ends of an axis, forming a linear molecule.

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  9. Molecular model - Wikipedia

    en.wikipedia.org/wiki/Molecular_model

    A molecular model is a physical model of an atomistic system that represents molecules and their processes. They play an important role in understanding chemistry and generating and testing hypotheses .