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Bromine monofluoride is a quite unstable interhalogen compound with the chemical formula BrF. It can be produced through the reaction of bromine trifluoride (or bromine pentafluoride) and bromine. Due to its lability, the compound can be detected but not isolated: [2] BrF 3 + Br 2 → 3 BrF BrF 5 + 2 Br 2 → 5 BrF Br 2(l) + F 2(g) → 2 BrF (g)
The well-characterized heavier halogens (chlorine, bromine, and iodine) all form mono-, tri-, and pentafluorides: XF, XF 3, and XF 5. Of the neutral +7 species, only iodine heptafluoride is known. [93] While chlorine and bromine heptafluorides are not known, the corresponding cations ClF + 6 and BrF + 6, extremely strong oxidizers, are. [94]
Carbon monofluoride (CF, CF x, or (CF) x), also called polycarbon monofluoride; Chlorine monofluoride, a volatile interhalogen compound with formula ClF; Iodine monofluoride, a chocolate-brown solid compound with formula IF; Hydrogen fluoride, a liquid or gas with boiling point at about 20 °C, HF; Nitrogen monofluoride, a metastable compound ...
The aluminium(I) cation reacts with hydrogen halides to form the following aluminium monohalides: [1] aluminium monofluoride (AlF) aluminium monochloride (AlCl) aluminium monobromide (AlBr) aluminium monoiodide (AlI) These compounds are only thermodynamically stable at high temperatures and low pressures in the singlet ground state. [7]
Bond energies to bromine tend to be lower than those to chlorine but higher than those to iodine, and bromine is a weaker oxidising agent than chlorine but a stronger one than iodine. This can be seen from the standard electrode potentials of the X 2 /X − couples (F, +2.866 V; Cl, +1.395 V; Br, +1.087 V; I, +0.615 V; At, approximately +0.3 V ...
Aluminium monofluoride, also known as fluoridoaluminium, is the chemical compound with the formula AlF. This elusive species is formed by the reaction between aluminium trifluoride and metallic aluminium at elevated temperatures but quickly reverts to the reactants when cooled. [ 1 ]
Bromine fluoride may refer to several compounds with the elements bromine and fluorine: Bromine monofluoride, BrF;
Many alkylating agents can be used instead of alkyl halides. For example, enones and epoxides can be used in presence of protons. The reaction typically employs a strong Lewis acid, such as aluminium chloride as catalyst, to increase the electrophilicity of the alkylating agent. [6]