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Polyhedral representation of spinel MgAl 2 O 4. Spinel (/ s p ɪ ˈ n ɛ l, ˈ s p ɪ n əl / [7]) is the magnesium/aluminium member of the larger spinel group of minerals. It has the formula MgAl 2 O 4 in the cubic crystal system. Its name comes from the Latin word spinella, a diminutive form of spine, in reference to its pointed crystals. [5]
The heterogeneity of spinel group members varies based on composition with ferrous and magnesium based members varying greatly as in solid solution, which requires similarly sized cations. However, ferric and aluminium based spinels are almost entirely homogeneous due to their large size difference.
In aluminium alloys containing magnesium, magnesium oxides (MgO), cuboids (MgAl 2 O 4-cuboid) and metallurgical spinel (MgAl 2 O 4-spinel) can form. They result from the reaction between magnesium and oxygen in the melt. More of them will form with time and temperature. Spinel can be highly detrimental because of its big size and high hardness.
The solubility of magnesium is very high in aluminium and reaches a maximum at 450 °C with 14% to 17% depending on the literature reference. At 34.5%, there is a Eutectic with Al 8 Mg 5 (sometimes referred to as Al 3 Mg 2), an intermetallic phase (-phase).
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Galaxite is the manganese (Mn) rich endmember of the aluminium (Al) series of the spinel group. Divalent iron (Fe) and magnesium (Mg) readily substitute for the manganese in the crystal structure. Trivalent iron may also substitute for the aluminium.