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Calcium borate (Ca 3 (BO 3) 2). It can be prepared by reacting calcium metal with boric acid. The resulting precipitate is calcium borate. A hydrated form occurs naturally as the minerals colemanite, nobleite and priceite. [citation needed] One of its uses is as a binder in some grades of hexagonal boron nitride for hot pressing.
Grade HBN contains a boron oxide binder; it is usable up to 550–850 °C in oxidizing atmosphere and up to 1600 °C in vacuum, but due to the boron oxide content is sensitive to water. Grade HBR uses a calcium borate binder and is usable at 1600 °C. Grades HBC and HBT contain no binder and can be used up to 3000 °C. [56]
The Borate Minerals are minerals which contain a borate anion group. The borate (BO 3) units may be polymerised similar to the SiO 4 unit of the silicate mineral class. This results in B 2 O 5, B 3 O 6, B 2 O 4 anions as well as more complex structures which include hydroxide or halogen anions. [2] The [B(O,OH) 4] − anion exists as well.
A binder or binding agent is any material or substance that holds or draws other materials together to form a cohesive whole mechanically, chemically, by adhesion or cohesion. More narrowly, binders are liquid or dough-like substances that harden by a chemical or physical process and bind fibres, filler powder and other particles added into it.
Calciborite, CaB 2 O 4, is a rare calcium borate mineral. It was first described in 1955 in the Novofrolovskoye copper–boron deposit, near Krasnoturinsk, Turinsk district, Northern Ural Mountains, Russia. [4] It occurs in a skarn deposit formed in limestone adjacent to a quartz diorite intrusive.
The orthoborate ion is known in the solid state, for example, in calcium orthoborate (Ca 2+) 3 ([BO 3] 3−) 2, [1] where it adopts a nearly trigonal planar structure. It is a structural analogue of the carbonate anion [CO 3] 2−, with which it is isoelectronic. Simple bonding theories point to the trigonal planar structure.
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Borate ions occur, alone or with other anions, in many borate and borosilicate minerals such as borax, boracite, ulexite (boronatrocalcite) and colemanite.Borates also occur in seawater, where they make an important contribution to the absorption of low frequency sound in seawater.