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An example of a linear alkylbenzene sulfonate (LAS) Linear alkylbenzene sulfonates (LAS) are prepared industrially by the sulfonation of linear alkylbenzenes (LABs), which can themselves be prepared in several ways. [2] In the most common route benzene is alkylated by long chain monoalkenes (e.g. dodecene) using hydrogen fluoride as a catalyst. [9]
Synthetic sulfonates are the most widely used detergents, as industrial oil, emulsifiers, demulsifiers, rust inhibitors, dispersants, surfactants for enhanced oil recovery, ore-floatation agents, and wetting agents, among others. LABs such as alkylbenzene, dialkylbenzene, and alkyltoluene are most commonly used to prepare sulfonate detergents. [4]
Linear alkylbenzene is sulfonated to produce linear alkylbenzene sulfonate (LAS), a biodegradable surfactant. LAS replaced branched dodecylbenzene sulfonates, which were phased out because they biodegrade more slowly.
Benzenesulfonic acid (conjugate base benzenesulfonate) is an organosulfur compound with the formula C 6 H 6 O 3 S.It is the simplest aromatic sulfonic acid.It forms white deliquescent sheet crystals or a white waxy solid that is soluble in water and ethanol, slightly soluble in benzene and insoluble in nonpolar solvents like diethyl ether.
The resulting sulfonic acid is then neutralized with base to give sodium alkylbenzenesulfonate, which is subsequently blended with other components to produce cleaning products. [1] Dodecylbenzene (and its isomers) are precursors to linear alkylbenzene sulfonate detergents. [2]
Sodium benzenesulfonate is an organic compound with the formula C 6 H 5 SO 3 Na.It is white, water-soluble solid, It is produced by the neutralization benzenesulfonic acid with sodium hydroxide.
The sulfonate ion. In organosulfur chemistry, a sulfonate is a salt, anion or ester of a sulfonic acid. Its formula is R−S(=O) 2 −O −, containing the functional group −S(=O) 2 −O −, where R is typically an organyl group, amino group or a halogen atom. Sulfonates are the conjugate bases of sulfonic acids.
Included are several fundamental benzene-based feedstocks such as ethylbenzene (precursor to styrene), cumene (precursor to phenol and acetone), linear alkylbenzene sulfonates (for detergents). [11] Sodium dodecylbenzene, obtained by alkylation of benzene with dodecene, is a precursor to linear alkylbenzene sulfonate detergents.