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Arumugam Manthiram (MUN-thee-rum; [6] born March 15, 1951) is an Indian-American materials scientist and engineer, best known for his identification of the polyanion class of lithium-ion battery cathodes, understanding of how chemical instability limits the capacity of layered oxide cathodes, and technological advances in lithium sulfur batteries.
The cell voltage of lithium-ion batteries with NMC cathodes is 3.6–3.7 V. [24] Arumugam Manthiram has reported that the relative positioning of the metals' 3d bands to the oxygen 2p band leads to each metal's role within NMC cathode materials. The manganese 3d band is above the oxygen 2p band, resulting in manganese's high chemical stability.
2016: Koichi Mizushima and Akira Yoshino received the NIMS Award from the National Institute for Materials Science, for Mizushima's discovery of the LiCoO 2 cathode material for the lithium-ion battery and Yoshino's development of the lithium-ion battery. [75] 2016: Z. Qi, and Gary Koenig reported a scalable method to produce sub-micrometer ...
The lithium nickel cobalt aluminium oxides (abbreviated as Li-NCA, LNCA, or NCA) are a group of mixed metal oxides. Some of them are important due to their application in lithium-ion batteries. NCAs are used as active material in the positive electrode (which is the cathode when the battery is discharged).
A lithium-ion or Li-ion battery is a type of rechargeable battery that uses the reversible intercalation of Li + ions into electronically conducting solids to store energy. In comparison with other commercial rechargeable batteries, Li-ion batteries are characterized by higher specific energy, higher energy density, higher energy efficiency, a longer cycle life, and a longer calendar life.
One of the main research efforts in the field of lithium-manganese oxide electrodes for lithium-ion batteries involves developing composite electrodes using structurally integrated layered Li 2 MnO 3, layered LiMnO 2, and spinel LiMn 2 O 4, with a chemical formula of x Li 2 MnO 3 • y Li 1+a Mn 2-a O 4 • z LiMnO 2, where x+y+z=1. The ...
LiFePO 4 is a 3.6 V lithium-ion battery cathode initially reported by John Goodenough and is structurally related to the mineral olivine and consists of a three dimensional lattice of an [FePO4] framework surrounding a lithium cation. The lithium cation sits in a one dimensional channel along the [010] axis of the crystal structure.
Arumugam Manthiram and John B. Goodenough first identified the polyanion class of cathode materials for lithium ion batteries. [9] [10] [11] LiFePO4 was then identified as a cathode material belonging to the polyanion class for use in batteries in 1996 by Padhi et al. [12] [13] Reversible extraction of lithium from LiFePO