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Each type of perfluoropolyether is synthesized differently: PFPE-K is obtained from HFPO by anionic polymerization.For PFPE-Y and PFBE-Z, photooxidation of hexafluoropropylene and tetrafluoroethylene, respectively, is applied.
PTFE is hydrophobic: neither water nor water-containing substances wet PTFE, as fluorocarbons exhibit only small London dispersion forces due to the low electric polarizability of fluorine. PTFE has one of the lowest coefficients of friction of any solid. Polytetrafluoroethylene is used as a non-stick coating for pans and other cookware.
A convenient, safe method for generating TFE is the pyrolysis of the sodium salt of pentafluoropropionic acid: [6]. C 2 F 5 CO 2 Na → C 2 F 4 + CO 2 + NaF. The depolymerization reaction – vacuum pyrolysis of PTFE at 650–700 °C (1,200–1,290 °F) in a quartz vessel – is a traditional laboratory synthesis of TFE.
PTFE has a higher melting point and is more crystalline than PCTFE, but the latter is stronger and stiffer. Though PCTFE has excellent chemical resistance, it is still less than that of PTFE. [22] PCTFE has lower viscosity, higher tensile strength and creep resistance than PTFE. [1] PCTFE is injection-moldable and extrudable, whereas PTFE is ...
PTFE tape used for different sized fittings PTFE tape for natural gas. There are two US standards for determining the quality of any thread seal tape. MIL-T-27730A (an obsolete military specification still commonly used in industry in the US) requires a minimum thickness of 3.5 mils and a minimum PTFE purity of 99%. [3]
Fluorinated polymers like PTFE and PVDF are especially thermally stable due to strong carbon-fluorine (C–F) bonds, the strongest in organic chemistry, which contribute to the durability of these materials under heat. PVDF is semi-crystalline, giving it a balance of rigidity and flexibility across temperatures from −35 °C to 160 °C.