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Chemistry Letters is a peer-reviewed scientific journal published by the Chemical Society of Japan. It specializes in the rapid publication of reviews and letters on all areas of chemistry. The editor-in-chief is Mitsuhiko Shionoya (University of Tokyo). According to the Journal Citation Reports, the journal has a 2014 impact factor of 1.23. [1]
The Sakurai reaction (also known as the Hosomi–Sakurai reaction) is the chemical reaction of carbon electrophiles (such as a ketone shown here) with allyltrimethylsilane catalyzed by strong Lewis acids.
Several approches to acylsilanes start with carboxylic acid derivatives. [1] Esters undergo reductive silylation en route to acylsilanes: RCO 2 Me + 2 tmsCl + Mg → RC(OMe)(Otms)(tms) + MgCl 2
m-MTDATA - whose full name is 4,4',4"-Tris(N-3-methylphenyl-N-phenyl-amino) triphenylamine - is an organic molecule belonging to the class of starburst molecules, [3] often used as a material for the production of organic electronic devices.
In organic chemistry, the Murai reaction is an organic reaction that uses C-H activation to create a new C-C bond between a terminal or strained internal alkene and an aromatic compound using a ruthenium catalyst. [1]
A recent review by Shenvi and coworkers, [8] proposed that the Mukaiyama hydration operates via the same principles as metal hydride hydrogen atom transfer (MH HAT), elucidated by Jack Halpern and Jack R. Norton in their studies on hydrogenation of anthracenes by syngas and Co 2 (CO) 8 [9] and the chemistry of vitamin B 12 mimics, [10 ...
Concerted metalation-deprotonation (CMD) is a mechanistic pathway through which transition-metal catalyzed C–H activation reactions can take place. In a CMD pathway, the C–H bond of the substrate is cleaved and the new C–Metal bond forms through a single transition state. [1]
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