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The work–energy principle states that an increase in the kinetic energy of a rigid body is caused by an equal amount of positive work done on the body by the resultant force acting on that body. Conversely, a decrease in kinetic energy is caused by an equal amount of negative work done by the resultant force.
This article uses the physics sign convention for work, where positive work is work done by the system. Using this convention, by the first law of thermodynamics, The yellow area represents the work done = + where W is work, U is internal energy, and Q is heat. [1] Pressure-volume work by the closed system is defined as:
In physics, force exerted equivocates work done. [3] The ability to do work can be either positive or negative depending on the direction of exertion relative to gravity. For example, a force exerted upwards, like lifting an object, creates positive work done on that object.
The non-mechanical work of force fields can have either positive or negative sign, work being done by the system on the surroundings, or vice versa. Work done by force fields can be done indefinitely slowly, so as to approach the fictive reversible quasi-static ideal, in which entropy is not created in the system by the process.
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The process does no pressure-volume work, since such work is defined by =, where P is pressure. The sign convention is such that positive work is performed by the system on the environment. If the process is not quasi-static, the work can perhaps be done in a volume constant thermodynamic process. [1]
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