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Photolysis occurs in the atmosphere as part of a series of reactions by which primary pollutants such as hydrocarbons and nitrogen oxides react to form secondary pollutants such as peroxyacyl nitrates. See Photochemical smog. The two most important photodissociation reactions in the troposphere are firstly:
PAN is produced in the atmosphere via photochemical oxidation of hydrocarbons to peroxyacetic acid radicals, which react reversibly with nitrogen dioxide (NO 2) to form PAN. [4]: 2680 Night-time reaction of acetaldehyde with nitrogen trioxide is another possible source. [4] Since there are no direct emissions, it is a secondary pollutant.
Photochemical smog, often referred to as "summer smog", is the chemical reaction of sunlight, nitrogen oxides and volatile organic compounds in the atmosphere, which leaves airborne particles and ground-level ozone. [21] Photochemical smog depends on primary pollutants as well as the formation of secondary pollutants.
Night-time reaction of aldehydes with nitrogen trioxide is another possible source. [ 6 ] : 2680 Since they dissociate quite slowly in the atmosphere into radicals and NO 2 , PANs are able to transport these unstable compounds far away from the urban and industrial origin.
In June to August, photochemical ozone production causes very high concentrations over the East Coast of the US and China. Ground-level ozone ( O 3 ), also known as surface-level ozone and tropospheric ozone , is a trace gas in the troposphere (the lowest level of the Earth's atmosphere ), with an average concentration of 20–30 parts per ...
Photogeochemical reactions are described by the same principles used to describe photochemical reactions in general, and may be classified similarly: Photosynthesis: in the most general sense, photosynthesis refers to any light-activated reaction for which the change in free energy (ΔG o ) is positive for the reaction itself (without ...
Photochemical immersion well reactor (50 mL) with a mercury-vapor lamp.. Photochemistry is the branch of chemistry concerned with the chemical effects of light. Generally, this term is used to describe a chemical reaction caused by absorption of ultraviolet (wavelength from 100 to 400 nm), visible (400–750 nm), or infrared radiation (750–2500 nm).
Atmospheric chemistry is a branch of atmospheric science that studies the chemistry of the Earth's atmosphere and that of other planets. This multidisciplinary approach of research draws on environmental chemistry, physics, meteorology, computer modeling, oceanography, geology and volcanology, climatology and other disciplines to understand both natural and human-induced changes in atmospheric ...