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PAN is produced in the atmosphere via photochemical oxidation of hydrocarbons to peroxyacetic acid radicals, which react reversibly with nitrogen dioxide (NO 2) to form PAN. [4]: 2680 Night-time reaction of acetaldehyde with nitrogen trioxide is another possible source. [4] Since there are no direct emissions, it is a secondary pollutant.
In June to August, photochemical ozone production causes very high concentrations over the East Coast of the US and China. Ground-level ozone ( O 3 ), also known as surface-level ozone and tropospheric ozone , is a trace gas in the troposphere (the lowest level of the Earth's atmosphere ), with an average concentration of 20–30 parts per ...
Photochemical immersion well reactor (50 mL) with a mercury-vapor lamp.. Photochemistry is the branch of chemistry concerned with the chemical effects of light. Generally, this term is used to describe a chemical reaction caused by absorption of ultraviolet (wavelength from 100 to 400 nm), visible (400–750 nm), or infrared radiation (750–2500 nm).
PANs are secondary pollutants, which means they are not directly emitted as exhaust from power plants or internal combustion engines, but they are formed from other pollutants by chemical reactions in the atmosphere. Free radical reactions catalyzed by ultraviolet light from the sun oxidize unburned non-methane [6]: 2679 hydrocarbons to ...
This wavelength regime has the highest cross section for this reaction (10 −17 cm 2 per oxygen molecule), and thus the rate of oxygen photodissociation per oxygen molecule decreases significantly at these altitudes, from more than 10 −7 per second (about once a month) at 100 km to 10 −8 per second (about once every few years) at 80 km . [4]
Photochemical reactions are initiated by the absorption of a photon, typically in the wavelength range 290–700 nm (at the surface of the Earth). The energy of an absorbed photon is transferred to electrons in the molecule and briefly changes their configuration (i.e., promotes the molecule from a ground state to an excited state). The excited ...
Atmospheric chemistry is a branch of atmospheric science that studies the chemistry of the Earth's atmosphere and that of other planets. This multidisciplinary approach of research draws on environmental chemistry, physics, meteorology, computer modeling, oceanography, geology and volcanology, climatology and other disciplines to understand both natural and human-induced changes in atmospheric ...
Photosynthetic water splitting (or oxygen evolution) is one of the most important reactions on the planet, since it is the source of nearly all the atmosphere's oxygen. Moreover, artificial photosynthetic water-splitting may contribute to the effective use of sunlight as an alternative energy-source.