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The equilibrium constant of a chemical reaction is the value of its reaction quotient at chemical equilibrium, a state approached by a dynamic chemical system after sufficient time has elapsed at which its composition has no measurable tendency towards further change. For a given set of reaction conditions, the equilibrium constant is ...
The Van 't Hoff equation relates the change in the equilibrium constant, K eq, of a chemical reaction to the change in temperature, T, given the standard enthalpy change, Δ r H ⊖, for the process. The subscript r {\displaystyle r} means "reaction" and the superscript ⊖ {\displaystyle \ominus } means "standard".
The relative activity of a species i, denoted a i, is defined [4] [5] as: = where μ i is the (molar) chemical potential of the species i under the conditions of interest, μ o i is the (molar) chemical potential of that species under some defined set of standard conditions, R is the gas constant, T is the thermodynamic temperature and e is the exponential constant.
Considering equilibrium states, M. Bailyn writes: "Each intensive variable has its own type of equilibrium." He then defines thermal equilibrium, mechanical equilibrium, and material equilibrium. Accordingly, he writes: "If all the intensive variables become uniform, thermodynamic equilibrium is said to exist." He is not here considering the ...
In the thermodynamics of equilibrium, a state function, function of state, or point function for a thermodynamic system is a mathematical function relating several state variables or state quantities (that describe equilibrium states of a system) that depend only on the current equilibrium thermodynamic state of the system [1] (e.g. gas, liquid, solid, crystal, or emulsion), not the path which ...
Polymer physics is the field of physics that studies polymers, ... and material properties of polymers. These experimental methods help the mathematical modeling of ...
Although the reduction in the number of variables is a useful simplification, the main advantage comes from the fact that the Helmholtz free energy is minimized at equilibrium with respect to any unconstrained internal variables for a closed system at constant temperature and volume. This follows directly from the principle of minimum energy ...
A polyester shirt Close-up of a polyester shirt SEM picture of a bend in a high-surface area polyester fiber with a seven-lobed cross section A drop of water on a water resistant polyester Polyesters can contain one ester linkage per repeat unit of the polymer, as in polyhydroxyalkanoates like polylactic acid , or they may have two ester ...