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Physical weathering, also called mechanical weathering or disaggregation, is the class of processes that causes the disintegration of rocks without chemical change. Physical weathering involves the breakdown of rocks into smaller fragments through processes such as expansion and contraction, mainly due to temperature changes.
Photogeochemical reactions are described by the same principles used to describe photochemical reactions in general, and may be classified similarly: Photosynthesis: in the most general sense, photosynthesis refers to any light-activated reaction for which the change in free energy (ΔG o ) is positive for the reaction itself (without ...
Photochemical immersion well reactor (50 mL) with a mercury-vapor lamp.. Photochemistry is the branch of chemistry concerned with the chemical effects of light. Generally, this term is used to describe a chemical reaction caused by absorption of ultraviolet (wavelength from 100 to 400 nm), visible (400–750 nm), or infrared radiation (750–2500 nm).
Photolysis occurs in the atmosphere as part of a series of reactions by which primary pollutants such as hydrocarbons and nitrogen oxides react to form secondary pollutants such as peroxyacyl nitrates. See Photochemical smog. The two most important photodissociation reactions in the troposphere are firstly:
On the other hand, 5.7 ± 1.2 Tmol of O 2 per year today oxidizes reduced gases in the atmosphere through photochemical reaction. [26] On the early Earth, there was visibly very little oxidative weathering of continents (e.g., a lack of red beds ), and so the weathering sink on oxygen would have been negligible compared to that from reduced ...
Atmospheric chemistry is a branch of atmospheric science that studies the chemistry of the Earth's atmosphere and that of other planets. This multidisciplinary approach of research draws on environmental chemistry, physics, meteorology, computer modeling, oceanography, geology and volcanology, climatology and other disciplines to understand both natural and human-induced changes in atmospheric ...
Photochemical reactions are initiated by the absorption of a photon, typically in the wavelength range 290–700 nm (at the surface of the Earth). The energy of an absorbed photon is transferred to electrons in the molecule and briefly changes their configuration (i.e., promotes the molecule from a ground state to an excited state ).
In chemical terms, actinism is the property of radiation that lets it be absorbed by a molecule and cause a photochemical reaction as a result. Albert Einstein was the first to correctly theorize that each photon would be able to cause only one molecular reaction. This distinction separates photochemical reactions from exothermic reduction ...