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A heterocyclic compound or ring structure is a cyclic compound that has atoms of at least two different elements as members of its ring(s). [1] Heterocyclic organic chemistry is the branch of organic chemistry dealing with the synthesis, properties, and applications of organic heterocycles .
This group typically excludes compounds in which either benzene is fused to another ring (bicyclic, tricyclic, polycyclic) [1] or includes a heteroatom, or where the methane connects to three or four benzenes. Ball-and-stick model of the benzhydryl radical. The benzhydryl radical can be abbreviated Ph 2 CH• or Bzh. [2]
Many simple aromatic rings have trivial names. They are usually found as substructures of more complex molecules ("substituted aromatics"). Typical simple aromatic compounds are benzene, indole, and pyridine. [1] [2] Simple aromatic rings can be heterocyclic if they contain non-carbon ring atoms, for example, oxygen, nitrogen, or sulfur.
There are two general types of metal-centered cycloaddition reactions: those in which the metal is incorporated into the cycle (a metallocycle), and those in which the metal is external to the cycle. These can be further divided into "true" cycloadditions (those that take place in a concerted fashion), and formal cycloadditions (those that take ...
The driving force for ring-opening and polymerization is strain relief. The reaction is believed to be a living polymerization due to the lack of competing reactions. Because the two benzene rings are in close proximity this cyclophane type also serves as guinea pig for photochemical dimerization reactions as illustrated by this example: [21]
An alkyne trimerisation is a [2+2+2] cycloaddition reaction in which three alkyne units (C≡C) react to form a benzene ring. The reaction requires a metal catalyst. The process is of historic interest as well as being applicable to organic synthesis. [1] Being a cycloaddition reaction, it has high atom economy.