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Atom economy. Atom economy (atom efficiency/percentage) is the conversion efficiency of a chemical process in terms of all atoms involved and the desired products produced. The simplest definition was introduced by Barry Trost in 1991 and is equal to the ratio between the mass of desired product to the total mass of reactants, expressed as a percentage.
The atom economy is calculated by = % The conservation of mass principle dictates that the total mass of the reactants is the same as the total mass of the products. In the above example, the sum of molecular masses of A, B, C and D should be equal to that of R, X, Y and Z.
The atom economy of a reaction is defined as the number of atoms from the starting materials that are incorporated into the final product. Atom economy can be viewed as an indicator of the “efficiency” of a given synthetic route. [3]
The Solvay process or ammonia–soda process is the major industrial process for the production of sodium carbonate (soda ash, Na 2 CO 3).The ammonia–soda process was developed into its modern form by the Belgian chemist Ernest Solvay during the 1860s. [1]
The total reaction may be diffusion controlled (the electron transfer step is faster than diffusion, every encounter leads to reaction) or activation controlled (the "equilibrium of association" is reached, the electron transfer step is slow, the separation of the successor complex is fast). The ligand shells around A and D are retained.
where A and B are reactants C is a product a, b, and c are stoichiometric coefficients,. the reaction rate is often found to have the form: = [] [] Here is the reaction rate constant that depends on temperature, and [A] and [B] are the molar concentrations of substances A and B in moles per unit volume of solution, assuming the reaction is taking place throughout the volume of the ...
The atomic ratio is a measure of the ratio of atoms of one kind (i) to another kind (j). A closely related concept is the atomic percent (or at.%), which gives the percentage of one kind of atom relative to the total number of atoms. [1]
This destabilization increases the reaction driving force, and the desire of the cycloalkyne to relieve its ring strain. Scheme of the Strain-promoted Azide-Alkyne Cycloaddition. This reaction proceeds as a concerted [3+2] cycloaddition to the triple bond in a cyclooctyne in the same mechanism as the Huisgen 1,3-dipolar cycloaddition ...