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Tables and datafiles are usually presented at a standard pressure of 1 bar or 1 atm, but in the case of steam and other industrially important gases, pressure may be included as a variable. Function values depend on the state of aggregation of the substance, which must be defined for the value to have any meaning.
An enthalpy–entropy chart, also known as the H–S chart or Mollier diagram, plots the total heat against entropy, [1] describing the enthalpy of a thermodynamic system. [2] A typical chart covers a pressure range of 0.01–1000 bar , and temperatures up to 800 degrees Celsius . [ 3 ]
The main feature of thermodynamic diagrams is the equivalence between the area in the diagram and energy. When air changes pressure and temperature during a process and prescribes a closed curve within the diagram the area enclosed by this curve is proportional to the energy which has been gained or released by the air.
The standard state of a material (pure substance, mixture or solution) is a reference point used to calculate its properties under different conditions.A degree sign (°) or a superscript Plimsoll symbol (⦵) is used to designate a thermodynamic quantity in the standard state, such as change in enthalpy (ΔH°), change in entropy (ΔS°), or change in Gibbs free energy (ΔG°).
= molar mass of Earth's air: 0.0289644 kg/mol; The value of subscript b ranges from 0 to 6 in accordance with each of seven successive layers of the atmosphere shown in the table below. The reference value for ρ b for b = 0 is the defined sea level value, ρ 0 = 1.2250 kg/m 3 or 0.0023768908 slug/ft 3.
In thermodynamics, a temperature–entropy (T–s) diagram is a thermodynamic diagram used to visualize changes to temperature (T ) and specific entropy (s) during a thermodynamic process or cycle as the graph of a curve. It is a useful and common tool, particularly because it helps to visualize the heat transfer during a process.
Figure 1. A thermodynamic model system. Differences in pressure, density, and temperature of a thermodynamic system tend to equalize over time. For example, in a room containing a glass of melting ice, the difference in temperature between the warm room and the cold glass of ice and water is equalized by energy flowing as heat from the room to the cooler ice and water mixture.
Entropy equivalent of one bit of information, equal to k times ln(2) [1] 10 −23: 1.381 × 10 −23 J⋅K −1: Boltzmann constant, entropy equivalent of one nat of information. 10 1: 5.74 J⋅K −1: Standard entropy of 1 mole of graphite [2] 10 33: ≈ 10 35 J⋅K −1: Entropy of the Sun (given as ≈ 10 42 erg⋅K −1 in Bekenstein (1973 ...