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It is the salt derived from the ammonium cation and the hydrosulfide anion.The salt exists as colourless, water-soluble, micaceous crystals. On Earth the compound is encountered mainly as a solution, not as the solid, but [NH 4]SH ice is believed to be a substantial component of the cloud decks of the gas-giant planets Jupiter and Saturn, with sulfur produced by its photolysis responsible for ...
Ammonium sulfite can be prepared by the reaction of ammonia with sulfur dioxide in aqueous solution: 2 NH 3 + SO 2 + H 2 O → (NH 4) 2 SO 3. Ammonium sulfite is produced in gas scrubbers, now obsolete, consisting of ammonium hydroxide to remove sulfur dioxide from emissions from power plants. The conversion is the basis of the Walther Process.
Ammonium sulfide forms yellow crystals, decomposing in water, of monoclinic system, space group P2 1 /c, cell parameters a = 0.5427 nm, b = 1.6226 nm, c = 0.9430 nm, β = 105.31°, Z = 4. [4] The compound can be stored under the mother liquor without air access. When dry, it decomposes quickly in the air. the compound emits sulfur intensively ...
The following chart shows the solubility of various ionic compounds in water at 1 atm pressure and room temperature (approx. 25 °C, 298.15 K). "Soluble" means the ionic compound doesn't precipitate, while "slightly soluble" and "insoluble" mean that a solid will precipitate; "slightly soluble" compounds like calcium sulfate may require heat to precipitate.
The electrolyte solution usually comprises a combination of cations, such as ammonium and potassium, and anions, including chloride and nitrate, which have similar mobility. [ 1 ] [ 3 ] The combination is chosen which does not react with any of the chemicals used in the cell.
Calcium carbonate precipitates as a solid, leaving ammonium sulfate in the solution. (NH 4) 2 CO 3 + CaSO 4 → (NH 4) 2 SO 4 + CaCO 3. Ammonium sulfate occurs naturally as the rare mineral mascagnite in volcanic fumaroles and due to coal fires on some dumps. [14] Ammonium sulfate is a byproduct in the production of methyl methacrylate. [15]
The blue colour of the solution is due to ammoniated electrons, which absorb energy in the visible region of light. The diffusivity of the solvated electron in liquid ammonia can be determined using potential-step chronoamperometry. [6] Solvated electrons in ammonia are the anions of salts called electrides. Na + 6 NH 3 → [Na(NH 3) 6] + + e −
All-solid-state electrolytes are furthermore divided into inorganic solid electrolyte (ISE), solid polymer electrolyte (SPE) and composite polymer electrolyte (CPE). On the other hand, a QSSE, also called gel polymer electrolyte (GPE), is a freestanding membrane that contains a certain amount of liquid component immobilized inside the solid matrix.