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Simplified diagram of the Copper–Chlorine cycle. The copper–chlorine cycle (Cu–Cl cycle) is a four-step thermochemical cycle for the production of hydrogen. The Cu–Cl cycle is a hybrid process that employs both thermochemical and electrolysis steps. It has a maximum temperature requirement of about 530 degrees Celsius.
Copper at red heat (300-400°C) combines directly with chlorine gas, giving (molten) copper(II) chloride. The reaction is very exothermic. [8] [15] Cu(s) + Cl 2 (g) → CuCl 2 (l) A solution of copper(II) chloride is commercially produced by adding chlorine gas to a circulating mixture of hydrochloric acid and copper. From this solution, the ...
Because this reaction is highly exothermic (238 kJ/mol), the temperature is monitored, to guard against thermal degradation of the catalyst. The reaction is as follows: CH 2 =CH 2 + 2 CuCl 2 → 2 CuCl + ClH 2 C-CH 2 Cl. The copper(II) chloride is regenerated by sequential reactions of the cuprous chloride with oxygen and then hydrogen chloride:
Infobox references. Carbon tetrachloride, also known by many other names (such as carbon tet for short and tetrachloromethane, also recognised by the IUPAC), is a chemical compound with the chemical formula CCl 4. It is a non-flammable, dense, colourless liquid with a "sweet" chloroform -like odour that can be detected at low levels.
Ellingham diagrams are a particular graphical form of the principle that the thermodynamic feasibility of a reaction depends on the sign of Δ G, the Gibbs free energy change, which is equal to Δ H − T Δ S, where Δ H is the enthalpy change and Δ S is the entropy change. The Ellingham diagram plots the Gibbs free energy change (Δ G) for ...
Wacker process. The Wacker process or the Hoechst-Wacker process (named after the chemical companies of the same name) refers to the oxidation of ethylene to acetaldehyde in the presence of palladium (II) chloride and copper (II) chloride as the catalyst. [1] This chemical reaction was one of the first homogeneous catalysis with organopalladium ...
Thermochemical cycles combine solely heat sources (thermo) with chemical reactions to split water into its hydrogen and oxygen components. [1] The term cycle is used because aside of water, hydrogen and oxygen, the chemical compounds used in these processes are continuously recycled. If work is partially used as an input, the resulting ...
Basic oxygen steelmaking. Basic oxygen steelmaking (BOS, BOP, BOF, or OSM), also known as Linz-Donawitz steelmaking or the oxygen converter process, [1] is a method of primary steelmaking in which carbon-rich molten pig iron is made into steel. Blowing oxygen through molten pig iron lowers the carbon content of the alloy and changes it into low ...