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Light stabilizer are used to inhibit polymer photo-oxidation, which is the combined result of the action of light and oxygen. Like autoxidation this is a free radical process, hence the antioxidants described above are effective inhibiting agents, however additional classes of additives are also beneficial, such as UV absorbers, quenchers of ...
In polymer science, dispersion polymerization is a heterogeneous polymerization process carried out in the presence of a polymeric stabilizer in the reaction medium. . Dispersion polymerization is a type of precipitation polymerization, meaning the solvent selected as the reaction medium is a good solvent for the monomer and the initiator, but is a non-solvent for the po
Hindered amine light stabilizers (HALS) are chemical compounds containing an amine functional group that are used as stabilizers in plastics and polymers. [1] These compounds are typically derivatives of tetramethylpiperidine and are primarily used to protect the polymers from the effects of photo-oxidation; as opposed to other forms of polymer degradation such as ozonolysis.
Polyvinyl alcohol (PVOH, PVA, or PVAl) is a water-soluble synthetic polymer. It has the idealized formula [CH 2 CH(OH)] n. It is used in papermaking, textile warp sizing, as a thickener and emulsion stabilizer in polyvinyl acetate (PVAc) adhesive formulations, in a variety of coatings, and 3D printing. It is colourless (white) and odorless.
Dyes and pigments are used in polymer materials to provide colour, however they can also effect the rate of photo-oxidation. Many absorb UV rays and in so doing protect the polymer, however absorption can cause the dyes to enter an excited state where they may attack the polymer or transfer energy to O 2 to form damaging singlet oxygen.
The polymer is manufactured in multiple viscosities, from a thin pourable liquid (when n is very low), to a thick rubbery semi-solid (when n is very high). PDMS molecules have quite flexible polymer backbones (or chains) due to their siloxane linkages, which are analogous to the ether linkages used to impart rubberiness to polyurethanes .
The polymer beads that result can range in size from 100 nm to 5 mm. The size is controlled by the stirring speed, the volume fraction of monomer, the concentration and identity of the stabilizers used, and the viscosities of the different components. The following equation derived empirically summarizes some of these interactions:
Azobisisobutyronitrile (abbreviated AIBN [1]) is an organic compound with the formula [(CH 3) 2 C(CN)] 2 N 2.This white powder is soluble in alcohols and common organic solvents but is insoluble in water.