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The boiling point elevation happens both when the solute is an electrolyte, such as various salts, and a nonelectrolyte. In thermodynamic terms, the origin of the boiling point elevation is entropic and can be explained in terms of the vapor pressure or chemical potential of the solvent. In both cases, the explanation depends on the fact that ...
Boiling point (°C) K b (°C⋅kg/mol) Freezing point (°C) K f (°C⋅kg/mol) Data source; Aniline: 184.3 3.69 –5.96 –5.87 K b & K f [1] Lauric acid:
A given pure compound has only one normal boiling point, if any, and a compound's normal boiling point and melting point can serve as characteristic physical properties for that compound, listed in reference books. The higher a compound's normal boiling point, the less volatile that compound is overall, and conversely, the lower a compound's ...
boiling point. Also vaporization point. The temperature at which a substance changes state from a liquid to a gas (or vapor). It depends on pressure and is usually specified for a given substance under standard conditions. boiling-point elevation The process by which a substance's boiling point is elevated by adding another substance. bond
The melting and boiling points correlate with the polarity of the molecules and their molecular weight. Some organic compounds, especially symmetrical ones, sublime . A well-known example of a sublimable organic compound is para-dichlorobenzene , the odiferous constituent of modern mothballs.
High vapor pressures indicate a high volatility, while high boiling points indicate low volatility. Vapor pressures and boiling points are often presented in tables and charts that can be used to compare chemicals of interest. Volatility data is typically found through experimentation over a range of temperatures and pressures.
The boiling point of water is typically considered to be 100 °C (212 °F; 373 K), especially at sea level. Pressure and a change in the composition of the liquid may alter the boiling point of the liquid. High elevation cooking generally takes longer since boiling point is a function of atmospheric pressure.
If the two layers are heated together, the system of layers will boil at 53.3 °C, which is lower than either the boiling point of chloroform (61.2 °C) or the boiling point of water (100 °C). The vapor will consist of 97.0% chloroform and 3.0% water regardless of how much of each liquid layer is present provided both layers are indeed present.