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[1] [2] [3] Introduced by Gilbert N. Lewis in his 1916 article The Atom and the Molecule, a Lewis structure can be drawn for any covalently bonded molecule, as well as coordination compounds. [4] Lewis structures extend the concept of the electron dot diagram by adding lines between atoms to represent shared pairs in a chemical bond.
The sodium chloride (NaCl) polymorph is most common. A cubic close-packed arrangement of chloride anions with rubidium cations filling the octahedral holes describes this polymorph. [4] Both ions are six-coordinate in this arrangement. The lattice energy of this polymorph is only 3.2 kJ/mol less than the following structure's. [5]
(a) The dot-and-cross diagram of the simplified LDQ structure of digermyne. The nuclei are as indicated and the electrons are denoted by either dots or crosses, depending on their relative spins. The ellipse in the centre indicates the relative disposition of the electrons around the germanium-germanium internuclear axis.
English: The crystal structure of sodium chloride, NaCl, a typical ionic compound. The __ purple spheres represent sodium cations, Na +, and the __ green spheres represent chloride anions, Cl −. The yellow stipples represent the electrostatic force in each ionic bond.
X-ray spectrometer developed by W. H. Bragg. In 1913 the structure of sodium chloride was determined by William Henry Bragg and William Lawrence Bragg. [2] [3] [4] This revealed that there were six equidistant nearest-neighbours for each atom, demonstrating that the constituents were not arranged in molecules or finite aggregates, but instead as a network with long-range crystalline order. [4]
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English: The crystal structure of sodium chloride, NaCl, a typical ionic compound. The __ purple spheres represent sodium cations, Na + , and the __ green spheres represent chloride anions, Cl − .