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Stoichiometry is not only used to balance chemical equations but also used in conversions, i.e., converting from grams to moles using molar mass as the conversion factor, or from grams to milliliters using density. For example, to find the amount of NaCl (sodium chloride) in 2.00 g, one would do the following:
The solution has 1 mole or 1 equiv Na +, 1 mole or 2 equiv Ca 2+, and 3 mole or 3 equiv Cl −. An earlier definition, used especially for chemical elements , holds that an equivalent is the amount of a substance that will react with 1 g (0.035 oz) of hydrogen , 8 g (0.28 oz) of oxygen , or 35.5 g (1.25 oz) of chlorine —or that will displace ...
For overall selectivity the same problem of the conflicting definitions exists. Generally, it is defined as the number of moles of desired product per the number of moles of undesired product (Definition 1 [3]). However, the definitions of the total amount of reactant to form a product per total amount of reactant consumed is used (Definition 2 ...
The equivalent weight of an element is the mass which combines with or displaces 1.008 gram of hydrogen or 8.0 grams of oxygen or 35.5 grams of chlorine. The equivalent weight of an element is the mass of a mole of the element divided by the element's valence. That is, in grams, the atomic weight of the element divided by the usual valence. [2]
Historically, the mole was defined as the amount of substance in 12 grams of the carbon-12 isotope.As a consequence, the mass of one mole of a chemical compound, in grams, is numerically equal (for all practical purposes) to the mass of one molecule or formula unit of the compound, in daltons, and the molar mass of an isotope in grams per mole is approximately equal to the mass number ...
For convenience in avoiding conversions in the imperial (or US customary units), some engineers adopted the pound-mole (notation lb-mol or lbmol), which is defined as the number of entities in 12 lb of 12 C. One lb-mol is equal to 453.592 37 g‑mol, [6] which is the same numerical value as the number of grams in an international avoirdupois pound.
Since 2019, a mole of any substance has been redefined in the SI as the amount of that substance containing an exactly defined number of particles, 6.022 140 76 × 10 23. The molar mass of a compound in g/mol thus is equal to the mass of this number of molecules of the compound in grams.
The term molality is formed in analogy to molarity which is the molar concentration of a solution. The earliest known use of the intensive property molality and of its adjectival unit, the now-deprecated molal, appears to have been published by G. N. Lewis and M. Randall in the 1923 publication of Thermodynamics and the Free Energies of Chemical Substances. [3]