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The electric dipole moment is a measure of the separation of positive and negative electrical charges within a system: that is, a measure of the system's overall polarity. The SI unit for electric dipole moment is the coulomb - meter (C⋅m).
Dipolar compound. In organic chemistry, a dipolar compound or simply dipole is an electrically neutral molecule carrying a positive and a negative charge in at least one canonical description. In most dipolar compounds the charges are delocalized. [1] Unlike salts, dipolar compounds have charges on separate atoms, not on positive and negative ...
In chemistry, polarity is a separation of electric charge leading to a molecule or its chemical groups having an electric dipole moment, with a negatively charged end and a positively charged end. Polar molecules must contain one or more polar bonds due to a difference in electronegativity between the bonded atoms.
Polarizability. Polarizability usually refers to the tendency of matter, when subjected to an electric field, to acquire an electric dipole moment in proportion to that applied field. It is a property of particles with an electric charge. When subject to an electric field, the negatively charged electrons and positively charged atomic nuclei ...
An example in organic chemistry of the role of geometry in determining dipole moment is the cis and trans isomers of 1,2-dichloroethene. In the cis isomer the two polar C−Cl bonds are on the same side of the C=C double bond and the molecular dipole moment is 1.90 D.
Typical dipole moments for simple diatomic molecules are in the range of 0 to 11 D. Molecules with symmetry point groups or containing inversion symmetry will not have a permanent dipole moment, while highly ionic molecular species have a very large dipole moment, e.g. gas-phase potassium bromide, KBr, with a dipole moment of 10.41 D. [3] A proton and an electron 1 Å apart have a dipole ...
Topological dipole moment, the measure of the topological defect charge distribution. The first order term (or the second term) of the multipole expansion of a function. The dielectric constant of a solvent; the measure of its capacity to break the covalent molecules into ions.
Hyperpolarizability. The hyperpolarizability, a nonlinear-optical property of a molecule, is the second order electric susceptibility per unit volume. [1] The hyperpolarizability can be calculated using quantum chemical calculations developed in several software packages. [2][3][4] See nonlinear optics.