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Most diethyl ether is produced as a byproduct of the vapor-phase hydration of ethylene to make ethanol.This process uses solid-supported phosphoric acid catalysts and can be adjusted to make more ether if the need arises: [9] Vapor-phase dehydration of ethanol over some alumina catalysts can give diethyl ether yields of up to 95%.
To convert from / to / ... Diethyl ether: 17.61 0.1344 Diethyl sulfide: 19.00 0.1214 Dimethyl ether: ... Ethanol: 12.18 0.08407 Ethyl acetate: 20.72
However, this synthesis risks the self-condensation of alcohol itself (e.g. ethanol self-condenses to form diethyl ether). A more common and higher-yielding reaction is the Williamson ether synthesis , where a phenol is converted by a strong base to the phenoxide ion, which can subsequently be reacted with an alkyl halide via nucleophilic ...
Diethyl ether: 0.713 34.5 2.16 –116.3 –1.79 K b & K f [1] Methanol [4] 0.79 64.7 Ethanol: 0.78 78.4 1.22 –114.6 –1.99 K b [2] Ethylene bromide: 2.18 133 6.43 ...
For example, ethyl methyl ether (CH 3 OC 2 H 5), diphenylether (C 6 H 5 OC 6 H 5). As for other organic compounds, very common ethers acquired names before rules for nomenclature were formalized. Diethyl ether is simply called ether, but was once called sweet oil of vitriol. Methyl phenyl ether is anisole, because it was originally found in ...
Good solvents are likely to be diethyl ether and hexane. (However, PE only dissolves at temperatures well above 100 °C.) (However, PE only dissolves at temperatures well above 100 °C.) Poly(styrene) has a solubility parameter of 9.1 cal 1/2 cm −3/2 , and thus ethyl acetate is likely to be a good solvent.
The order of addition of the reagents of the Mitsunobu reaction can be important. Typically, one dissolves the alcohol, the carboxylic acid, and triphenylphosphine in tetrahydrofuran or other suitable solvent (e.g. diethyl ether), cool to 0 °C using an ice-bath, slowly add the DEAD dissolved in THF, then stir at room temperature for several hours.
MSDS for diethyl ether is available at Mallinckrodt Baker. Structure and properties. Structure and properties Index of refraction, n D: 1.3497 at 24.8 °C