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Optical rotation, also known as polarization rotation or circular birefringence, is the rotation of the orientation of the plane of polarization about the optical axis of linearly polarized light as it travels through certain materials. Circular birefringence and circular dichroism are the manifestations of optical activity.
A polarimeter [1] is a scientific instrument used to measure optical rotation: the angle of rotation caused by passing linearly polarized light through an optically active substance. [ 2 ] Some chemical substances are optically active, and linearly polarized (uni-directional) light will rotate either to the left (counter-clockwise) or right ...
Kerr rotation and Kerr ellipticity are changes in the polarization of incident light which comes in contact with a gyromagnetic material. Kerr rotation is a rotation in the plane of polarization of transmitted light, and Kerr ellipticity is the ratio of the major to minor axis of the ellipse traced out by elliptically polarized light on the plane through which it propagates.
Specific rotation is an intensive property, distinguishing it from the more general phenomenon of optical rotation. As such, the observed rotation (α) of a sample of a compound can be used to quantify the enantiomeric excess of that compound, provided that the specific rotation ([α]) for the enantiopure compound is known.
A simple polarimeter to measure this rotation consists of a long tube with flat glass ends, into which the sample is placed. At each end of the tube is a Nicol prism or other polarizer. Light is shone through the tube, and the prism at the other end, attached to an eye-piece, is rotated to arrive at the region of complete brightness or that of ...
Faraday rotation is an important tool in astronomy for the measurement of magnetic fields, which can be estimated from rotation measures given a knowledge of the electron number density. [14] In the case of radio pulsars , the dispersion caused by these electrons results in a time delay between pulses received at different wavelengths, which ...
In optics, optical rotatory dispersion is the variation of the specific rotation of a medium with respect to the wavelength of light. Usually described by German physicist Paul Drude 's empirical relation: [ 1 ]
Visulization of flux through differential area and solid angle. As always ^ is the unit normal to the incident surface A, = ^, and ^ is a unit vector in the direction of incident flux on the area element, θ is the angle between them.