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2,3-Dichloro-5,6-dicyano-1,4-benzoquinone (or DDQ) is the chemical reagent with formula C 6 Cl 2 (CN) 2 O 2. This oxidant is useful for the dehydrogenation of alcohols, [3] phenols, [4] and steroid ketones. [5] DDQ decomposes in water, but is stable in aqueous mineral acid. [6]
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(1) Fmoc-protected amino group, (2) benzyl ester protected carboxyl group and (3) tert-butyl ether protected phenolic hydroxyl group of Tyrosine. Orthogonal protection is a strategy allowing the specific deprotection of one protective group in a multiply-protected structure.
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The o-hydroxyphenacyl PPG has been introduced as an alternative with absorption band shifted closer towards the visible region, however it has slightly lower quantum yields of deprotection (generally 0.1-0.3) due to excited state proton transfer available as an alternative deactivation pathway. [29]
The original form of the pattern, appearing in Pattern Languages of Program Design 3, [2] has data races, depending on the memory model in use, and it is hard to get right. Some consider it to be an anti-pattern. [3] There are valid forms of the pattern, including the use of the volatile keyword in Java and explicit memory barriers in C++. [4]
The unsubstituted compound can be prepared by oxidation of 2,2'-dipyrrolemethane with 2,3-dichloro-5,6-dicyano-1,4-benzoquinone (DDQ) at −78 °C in dry dichloromethane solution. [1] An alternative synthesis that avoids the oxidation step is the condensation of 2-formyl pyrrole and pyrrole catalyzed by trifluoroacetic acid , followed by ...