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In organic chemistry, ethenolysis is a chemical process in which internal olefins are degraded using ethylene (H 2 C=CH 2) as the reagent. The reaction is an example of cross metathesis . The utility of the reaction is driven by the low cost of ethylene as a reagent and its selectivity.
In organic chemistry, olefin metathesis is an organic reaction that entails the redistribution of fragments of alkenes (olefins) by the scission and regeneration of carbon-carbon double bonds. [ 1 ] [ 2 ] Because of the relative simplicity of olefin metathesis, it often creates fewer undesired by-products and hazardous wastes than alternative ...
The mechanism of homogeneous ring-opening metathesis polymerization is well-studied. It is similar to any olefin metathesis reaction. Initiation occurs by forming an open coordination site on the catalyst. Propagation happens via a metallacycle intermediate formed after a 2+2 cycloaddition. When using a G3 catalyst, 2+2 cycloaddition is the ...
In the 1960s, ruthenium trichloride was found to catalyze olefin metathesis. Processes were commercialized based on these discoveries. These ill-defined but highly active homogeneous catalysts remain in industrial use. [6] The first well-defined ruthenium catalyst was reported in 1992. [7] It was prepared from RuCl 2 (PPh 3) 4 and ...
Ring-closing metathesis (RCM) is a widely used variation of olefin metathesis in organic chemistry for the synthesis of various unsaturated rings via the intramolecular metathesis of two terminal alkenes, which forms the cycloalkene as the E-or Z-isomers and volatile ethylene.
Salt metathesis is a common technique for exchanging counterions. The choice of reactants is guided by a solubility chart or lattice energy. HSAB theory can also be used to predict the products of a metathesis reaction. Salt metathesis is often employed to obtain salts that are soluble in organic solvents.
Many mechanisms exist reflecting the myriad types of cross-couplings, including those that do not require metal catalysts. [7] Often, however, cross-coupling refers to a metal-catalyzed reaction of a nucleophilic partner with an electrophilic partner. Mechanism proposed for Kumada coupling (L = Ligand, Ar = Aryl).
An enyne metathesis is an organic reaction taking place between an alkyne and an alkene with a metal carbene catalyst forming a butadiene. This reaction is a variation of olefin metathesis. [1] The general scheme is given by scheme 1: When the reaction is intramolecular (in an enyne) it is called ring-closing enyne metathesis or RCEYM (scheme 2):