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[1] [2] For example, the Gibbs free energy of a compound in the area of thermochemistry is often quantified in units of kilojoules per mole (symbol: kJ·mol −1 or kJ/mol), with 1 kilojoule = 1000 joules. [3] Physical quantities measured in J·mol −1 usually describe quantities of energy transferred during phase transformations or chemical ...
R ∗ = 8.314 32 × 10 3 N⋅m⋅kmol −1 ⋅K −1 = 8.314 32 J⋅K −1 ⋅mol −1. Note the use of the kilomole, with the resulting factor of 1000 in the constant. The USSA1976 acknowledges that this value is not consistent with the cited values for the Avogadro constant and the Boltzmann constant. [ 13 ]
1 J·m 3 /mol 2 = 1 m 6 ·Pa/mol 2 = 10 L 2 ·bar/mol 2. 1 L 2 atm/mol 2 = 0.101325 J·m 3 /mol 2 = 0.101325 Pa·m 6 /mol 2. 1 dm 3 /mol = 1 L/mol = 1 m 3 /kmol = 0.001 m 3 /mol (where kmol is kilomoles = 1000 moles)
As typically measured, one kcal/mol represents a temperature increase of one degree Celsius in one liter of water (with a mass of 1 kg) resulting from the reaction of one mole of reagents. In SI units, one kilocalorie per mole is equal to 4.184 kilojoules per mole (kJ/mol), which comes to approximately 6.9477 × 10 −21 joules per molecule, or ...
The standard enthalpy of formation is measured in units of energy per amount of substance, usually stated in kilojoule per mole (kJ mol −1), but also in kilocalorie per mole, joule per mole or kilocalorie per gram (any combination of these units conforming to the energy per mass or amount guideline).
Although Boltzmann first linked entropy and probability in 1877, the relation was never expressed with a specific constant until Max Planck first introduced k, and gave a more precise value for it (1.346 × 10 −23 J/K, about 2.5% lower than today's figure), in his derivation of the law of black-body radiation in 1900–1901. [11]
These tables list values of molar ionization energies, measured in kJ⋅mol −1. This is the energy per mole necessary to remove electrons from gaseous atoms or atomic ions. The first molar ionization energy applies to the neutral atoms.
For gases, departure from 3 R per mole of atoms is generally due to two factors: (1) failure of the higher quantum-energy-spaced vibration modes in gas molecules to be excited at room temperature, and (2) loss of potential energy degree of freedom for small gas molecules, simply because most of their atoms are not bonded maximally in space to ...