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Ethylene has long represented the major nonfermentative precursor to ethanol. The original method entailed its conversion to diethyl sulfate, followed by hydrolysis. The main method practiced since the mid-1990s is the direct hydration of ethylene catalyzed by solid acid catalysts: [18] C 2 H 4 + H 2 O → CH 3 CH 2 OH
Ethylene glycol is produced from ethylene (ethene), via the intermediate ethylene oxide. Ethylene oxide reacts with water to produce ethylene glycol according to the chemical equation. C 2 H 4 O + H 2 O → HO−CH 2 CH 2 −OH. This reaction can be catalyzed by either acids or bases, or can occur at neutral pH under elevated temperatures. The ...
The main differences between each of them concerns the catalyst employed, design of the reactor and strategies to achieve higher conversion rates. [1] Olefins are useful precursors to myriad products. Steam cracking is the core technology that supports the largest scale chemical processes, i.e. ethylene and propylene. [2]
The chief use of ethane is the production of ethylene (ethene) by steam cracking. Steam cracking of ethane is fairly selective for ethylene, while the steam cracking of heavier hydrocarbons yields a product mixture poorer in ethylene and richer in heavier alkenes (olefins), such as propene (propylene) and butadiene, and in aromatic hydrocarbons.
Depending on the amount, a substance can be favorable or unfavorable for a chemical process. For example, in the production of ethylene, a small amount of chemisorbed chlorine will act as a promoter by improving Ag-catalyst selectivity towards ethylene over CO 2, while too much chlorine will act as a poison. [6]
The reaction usually involves strong acid as catalyst. [19] The first step in hydration often involves formation of a carbocation. The net result of the reaction will be an alcohol. The reaction equation for hydration of ethylene is: H 2 C=CH 2 + H 2 O→ H 3 C-CH 2 OH Example of hydrohalogenation: addition of HBr to an alkene
The major industrial route involves the reaction of ethylene and acetic acid with oxygen in the presence of a palladium catalyst. [6] 2 C 2 H 4 + 2 CH 3 CO 2 H + O 2 → 2 CH 3 CO 2 CHCH 2 + 2 H 2 O. This method has replaced the addition of acetic acid to acetylene. The main side reaction is the combustion of organic precursors.
General chemical structure of a polyketone. Polyketones are a family of high-performance thermoplastic polymers. The polar ketone groups in the polymer backbone of these materials gives rise to a strong attraction between polymer chains, which increases the material's melting point (255 °C for copolymer (carbon monoxide ethylene), 220 °C for terpolymer (carbon monoxide, ethylene, propylene).