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In chemistry and atomic physics, an electron shell may be thought of as an orbit that electrons follow around an atom's nucleus.The closest shell to the nucleus is called the "1 shell" (also called the "K shell"), followed by the "2 shell" (or "L shell"), then the "3 shell" (or "M shell"), and so on further and further from the nucleus.
In general, subshells with the same n + l value have similar energies, but the s-orbitals (with l = 0) are exceptional: their energy levels are appreciably far from those of their n + l group and are closer to those of the next n + l group. This is why the periodic table is usually drawn to begin with the s-block elements. [6]
Electron atomic and molecular orbitals A Bohr diagram of lithium. In atomic physics and quantum chemistry, the electron configuration is the distribution of electrons of an atom or molecule (or other physical structure) in atomic or molecular orbitals. [1]
See illustration of a cross-section of these nested shells, at right. The s orbitals for all n numbers are the only orbitals with an anti-node (a region of high wave function density) at the center of the nucleus. All other orbitals (p, d, f, etc.) have angular momentum, and thus avoid the nucleus (having a wave node at the nucleus).
For each atom the subshells are given first in concise form, then with all subshells written out, followed by the number of electrons per shell. For phosphorus (element 15) as an example, the concise form is [Ne] 3s 2 3p 3.
Thus the s, p, d, and f subshells contain 1, 3, 5, and 7 orbitals each. Each of these orbitals can accommodate up to two electrons (with opposite spins), forming the basis of the periodic table . Other magnetic quantum numbers are similarly defined, such as m j for the z -axis component the total electronic angular momentum j , [ 1 ] and m I ...
The three dumbbell-shaped p-orbitals have equal energy and are oriented mutually perpendicularly (or orthogonally). The p-orbitals oriented in the z-direction (p z) can overlap end-on forming a bonding (symmetrical) σ orbital and an antibonding σ* molecular orbital. In contrast to the sigma 1s MO's, the σ 2p has some non-bonding electron ...
The wavefunctions of these orbitals take the form of spherical harmonics, and so are described by Legendre polynomials. The several orbitals relating to the different (integer) values of ℓ are sometimes called sub-shells —referred to by lowercase Latin letters chosen for historical reasons—as shown in the table "Quantum subshells for the ...