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Usopp awakened his Observation Haki during the latter half of the Dressrosa revolt, as he was able to see auras of Luffy, Law, and Sugar, who were in the royal palace, from the old King's Plateau near the Corrida Colosseum. With this, he was able to pinpoint Sugar's location and snipe her down from such a distance.
The crew reunites with Jimbei, revealed to be indebted to Big Mom but intent on defecting to Luffy's crew. They ally with Capone Bege to assassinate Big Mom at the wedding, though the plan goes awry. As the crew attempts to escape, Luffy defeats her general Charlotte Katakuri, discovering an advanced application of Observation Haki in the process.
After activating Gear Fourth, Luffy manages to deal some damage to Katakuri, having realised the latter has been using his advance Observation Haki to avoid Luffy's attack while making it appear that he was immune to Armament Haki. However, Luffy loses the upper hand when Katakuri regains his composure.
Luffy and Hyogoro are confronted by Alpacaman and Madilloman, a armadillo SMILE Fruit Gifter. Luffy uses his advance Observation Haki to avoid Madilloman's attacks while also giving Hyogoro instructions to avoid attacks from Alpacaman as Luffy continues trying to use an advanced Armament Haki technique.
Law gets knocked out by Vergo who had a bamboo stick with him imbued with Haki. Caesar tells his men to tie up the Straw Hats and G-5. Meanwhile Chopper is looking for a way to cure the children. Zoro's group are waiting for Sanji to rescue the samurai's torso. Sanji uses Haki to find the body and realizes it is in a shark's mouth.
Roronoa Zoro (ロロノア・ゾロ, Roronoa Zoro, spelled as "Roronoa Zolo" in some English adaptations), also known as "Pirate Hunter" Zoro (海賊狩りのゾロ, Kaizoku-Gari no Zoro), is a fictional character created by Japanese manga artist Eiichiro Oda who appears in the manga series and media franchise One Piece.
When Sandersonia plans on breaking the petrified Marguerite in order to cause Luffy pain, he screams for her to stop, forcing her to stop and causing many of the assembled warriors to faint by using a special and rare kind of Haki Hancock identifies as a Conqueror's Spirit. With Margaret safe, Luffy prepares to fight at full power.
Luffy fights Largo, but becomes trapped when he turns his entire body into a net. Luffy uses Third Gear to inflate and burst the net before defeating Largo with Gigant Pistol, destroying his ship in the process. Boss saves Luffy from falling into the sea and then starts fighting him in a rematch that lasts for hours.