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Cycloalkene. In organic chemistry, a cycloalkene or cycloolefin is a type of alkene hydrocarbon which contains a closed ring of carbon atoms and either one or more double bonds, but has no aromatic character. Some cycloalkenes, such as cyclobutene and cyclopentene, can be used as monomers to produce polymer chains. [ 1 ]
Cycloalkane. Ball-and-stick model of cyclobutane. In organic chemistry, the cycloalkanes (also called naphthenes, but distinct from naphthalene) are the monocyclic saturated hydrocarbons. [1] In other words, a cycloalkane consists only of hydrogen and carbon atoms arranged in a structure containing a single ring (possibly with side chains), and ...
5. H. 10. C5H10 is the molecular formula of 13 hydrocarbon isomers (represented by their CAS numbers on the chart). They can be divided into cycloalkanes and alkenes.
Alkyl group. In organic chemistry, an alkyl group is an alkane missing one hydrogen. [1] The term alkyl is intentionally unspecific to include many possible substitutions. An acyclic alkyl has the general formula of −CnH2n+1. A cycloalkyl group is derived from a cycloalkane by removal of a hydrogen atom from a ring and has the general formula ...
RXNO:0000006. Diels–Alder reaction, simplest example. In organic chemistry, the Diels–Alder reaction is a chemical reaction between a conjugated diene and a substituted alkene, commonly termed the dienophile, to form a substituted cyclohexene derivative. It is the prototypical example of a pericyclic reaction with a concerted mechanism.
Cycloalkanes and aromatic compounds can be treated as the main parent chain of the compound, in which case the positions of substituents are numbered around the ring structure. For example, the three isomers of xylene CH 3 C 6 H 4 CH 3 , commonly the ortho- , meta- , and para- forms, are 1,2-dimethylbenzene, 1,3-dimethylbenzene, and 1,4 ...
Ring strain. In organic chemistry, ring strain is a type of instability that exists when bonds in a molecule form angles that are abnormal. Strain is most commonly discussed for small rings such as cyclopropanes and cyclobutanes, whose internal angles are substantially smaller than the idealized value of approximately 109°.
Conformational isomerism. Rotation about single bond of butane to interconvert one conformation to another. The gauche conformation on the right is a conformer, while the eclipsed conformation on the left is a transition state between conformers. Above: Newman projection; below: depiction of spatial orientation.