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Acetonitrile is less basic than DMSO, and, so, in general, acids are weaker and bases are stronger in this solvent. Some pK a values at 25 °C for acetonitrile (ACN) [37] [38] [39] and dimethyl sulfoxide (DMSO). [40] are shown in the following tables. Values for water are included for comparison.
These values below are pK a values determined in dimethylsulfoxide (DMSO), which has a broader useful range (~0 to ~35) than values determined in water (~0 to ~14) and better reflect the basicity of the carbanions in typical organic solvents. Values below less than 0 or greater than 35 are indirectly estimated; hence, the numerical accuracy of ...
As the name suggests, a non-nucleophilic base is a sterically hindered organic base that is a poor nucleophile.Normal bases are also nucleophiles, but often chemists seek the proton-removing ability of a base without any other functions.
Propylamine, also known as n-propylamine, is an amine with the chemical formula CH 3 (CH 2) 2 NH 2. [1] It is a colorless volatile liquid. [2] Propylamine is a weak base. Its K b (base dissociation constant) is 4.7 × 10 −4.
Periodic table of the chemical elements showing the most or more commonly named sets of elements (in periodic tables), and a traditional dividing line between metals and nonmetals. The f-block actually fits between groups 2 and 3 ; it is usually shown at the foot of the table to save horizontal space.
Tetramethylguanidine is an organic compound with the formula HNC(N(CH 3) 2) 2. This colourless liquid is a strong base, as judged by the high pK a of its' conjugate acid. [2] It was originally prepared from tetramethylthiourea via S-methylation and amination, but alternative methods start from cyanogen iodide. [3]
It can be used to form various organolithium compounds, including acetylides [3] or lithium enolates. [2] where Me = CH 3. As such, it finds use in a range of coupling reactions, particularly carbon-carbon bond forming reactions such as the Fráter–Seebach alkylation and mixed Claisen condensations.
This compound is a diamine in which the two dimethylamino groups are attached on the same side (peri position) of a naphthalene ring. This molecule has several very interesting properties; one is its very high basicity; another is its spectroscopic properties.