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The tangent construction shown above is rarely used in interpreting the stress-strain curves of metals. However, it is popular for analysis of the tensile drawing of polymers. [4] [5] (since it allows study of the regime of stable necking). It may be noted that, for polymers, the strain is commonly expressed as a “draw ratio”, rather than a ...
Draw resonance has not been found to be a function of the flow rate, however. A polymer melt approaching a Newtonian fluid such as PET can have a drawdown ratio of around 20, whereas highly shear thinning and viscoelastic polymer melts such as polyethylene, polystyrene, and polypropylene may have critical drawdown ratios as low as 3.
The Mayo–Lewis equation or copolymer equation in polymer chemistry describes the ... The reactivity ratio for each propagating chain end is defined as the ratio of ...
Polymer nomenclature is generally based upon the type of monomer residues comprising the polymer. A polymer which contains only a single type of repeat unit is known as a homopolymer, while a polymer containing two or more types of repeat units is known as a copolymer. [22] A terpolymer is a copolymer which contains three types of repeat units ...
In polymer chemistry, polymerization (American English), or polymerisation (British English), is a process of reacting monomer molecules together in a chemical reaction to form polymer chains or three-dimensional networks. [1] [2] [3] There are many forms of polymerization [4] and different systems exist to categorize them. IUPAC definition for ...
The synthesis and processing of polyacetylene films affects the properties. Increasing the catalyst ratio creates thicker films with a greater draw ratio, allowing them to be stretched further. [8] Lower catalyst loadings leads to the formation of dark red gels, which can be converted to films by cutting and pressing between glass plates. [20]
In shallow drawing, the depth of drawing is less than the smallest dimension of the hole. Bar, tube, and wire drawing all work upon the same principle: the starting stock is drawn through a die to reduce its diameter and increase its length. Usually, the die is mounted on a draw bench. The starting end of the workpiece is narrowed or pointed to ...
The number average molecular weight, M n, of the polymer resulting from such a system could be calculated by the amount of consumed monomer and the initiator used for the polymerization, as the degree of polymerization would be the ratio of the moles of the monomer consumed to the moles of the initiator added.