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The amount of strain in the stable neck is called the natural draw ratio [6] because it is determined by the material's hardening characteristics, not the amount of drawing imposed on the material. Ductile polymers often exhibit stable necks because molecular orientation provides a mechanism for hardening that predominates at large strains. [7]
Semi-crystalline polymers such as polyethylene show brittle fracture under stress if exposed to stress cracking agents. In such polymers, the crystallites are connected by the tie molecules through the amorphous phase. The tie molecules play an important role in the mechanical properties of the polymer through the transferring of load.
Draw resonance has not been found to be a function of the flow rate, however. A polymer melt approaching a Newtonian fluid such as PET can have a drawdown ratio of around 20, whereas highly shear thinning and viscoelastic polymer melts such as polyethylene, polystyrene, and polypropylene may have critical drawdown ratios as low as 3.
Polythiazyl caught Heeger's interest as a chain-like metallic material, and he collaborated with Alan MacDiarmid who had previous experience with this material. By the early 1970s, this polymer was known to be superconductive at low temperatures. [9] Shirakawa, Heeger, and MacDiarmid collaborated on further development of polyacetylene. [8]
Material is generally annealed between each drawing pass to increase its ductility and remove internal stresses produced during the cold working. Annealing : This is a thermal treatment generally used to soften the material being drawn; to modify the microstructure, the mechanical properties, and the machining characteristics of the steel; and ...
Blind holes are created by pins that are supported at only one end; hence such pins should not be long. Longer pins will deflect more and be pushed by the pressure of the molten plastic material during molding. It is recommended that hole depth-to-diameter ratio should not be more than 2.
The density of such boundaries is lower in polymers with very low crystallinity (amorphous polymer) or very high degree of crystalline polymers, consequentially, the transparency is higher. [5] For example, atactic polypropylene is usually amorphous and transparent while syndiotactic polypropylene, which has crystallinity ~50%, is opaque. [ 30 ]
Die swell occurs in instances of polymer extrusion, in which a stream of polymeric material is forced through a die, a specialized tool in manufacturing to shape or cut polymeric materials. Die swell is an instance where a polymer stream is compressed by entrance into a die, and is followed by a partial recovery or "swell" back to the former ...