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The Reformatsky reaction (sometimes transliterated as Reformatskii reaction) is an organic reaction which condenses aldehydes or ketones with α-halo esters using metallic zinc to form β-hydroxy-esters: [1] [2] The Reformatsky reaction. The organozinc reagent, also called a 'Reformatsky enolate', is prepared by treating an alpha-halo ester ...
The Waelz process is a method of recovering zinc and other relatively low boiling point metals from metallurgical waste (typically electric arc furnace flue dust) and other recycled materials using a rotary kiln (waelz kiln). The zinc enriched product is referred to as waelz oxide, and the reduced zinc by product as waelz slag.
This organic reaction can be employed to convert α-haloester and ketone or aldehyde to a β-hydroxyester. Acid is needed to protonate the resulting alkoxide during work up. The initial step is an oxidative addition of zinc metal into the carbon-halogen bond, thus forming a carbon-zinc enolate.
n.o.s. = not otherwise specified meaning a collective entry to which substances, mixtures, solutions or articles may be assigned if a) they are not mentioned by name in 3.2 Dangerous Goods List AND b) they exhibit chemical, physical and/or dangerous properties corresponding to the Class, classification code, packing group and the name and description of the n.o.s. entry [2]
Raney nickel, platinum on carbon, or zinc dust and formic acid or ammonium formate [6] α,β-Unsaturated nitro compounds can be reduced to saturated amines by: Catalytic hydrogenation over palladium-on-carbon; Iron metal; Lithium aluminium hydride [27] (Note: Hydroxylamines and oximes are typical impurities.)
Metal fume fever, also known as brass founders' ague, brass shakes, [1] zinc shakes, galvie flu, galvo poisoning, metal dust fever, welding shivers, or Monday morning fever, [2] is an illness primarily caused by exposure to chemicals such as zinc oxide (ZnO), aluminium oxide (Al 2 O 3), or magnesium oxide (MgO) which are produced as byproducts in the fumes that result when certain metals are ...
It forms on the surface of low-melting-point metals such as tin, lead, zinc or aluminium or alloys by oxidation of the metal. For higher melting point metals and alloys such as steel and silver, oxidized impurities melt and float making them easy to pour off. With wrought iron, hammering and later rolling remove some dross. [1]
Data conversion is the conversion of computer data from one format to another. Throughout a computer environment, data is encoded in a variety of ways. For example, computer hardware is built on the basis of certain standards, which requires that data contains, for example, parity bit checks.