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Solutions of C 60 can be oxygenated to the epoxide C 60 O. Ozonation of C 60 in 1,2-xylene at 257K gives an intermediate ozonide C 60 O 3, which can be decomposed into 2 forms of C 60 O. Decomposition of C 60 O 3 at 296 K gives the epoxide, but photolysis gives a product in which the O atom bridges a 5,6-edge.
The family is named after buckminsterfullerene (C 60), the most famous member, which in turn is named after Buckminster Fuller. The closed fullerenes, especially C 60, are also informally called buckyballs for their resemblance to the standard ball of association football ("soccer"). Nested closed fullerenes have been named bucky onions.
C 60 in solution C 60 in extra virgin olive oil showing the characteristic purple color of pristine C 60 solutions. The solubility of fullerenes is generally low. Carbon disulfide dissolves 8g/L of C60, and the best solvent (1-chloronaphthalene) dissolves 53 g/L. up Still, fullerenes are the only known allotrope of carbon that can be dissolved in common solvents at room temperature.
Polyfullerene is a basic polymer of the C 60 monomer group, in which fullerene segments are connected via covalent bonds into a polymeric chain without side or bridging groups. They are called intrinsic polymeric fullerenes, or more often all C 60 polymers. Fullerene can be part of a polymer chain in many different ways.
Fullerene or C 60 is soccer-ball-shaped or I h with 12 pentagons and 20 hexagons. According to Euler's theorem these 12 pentagons are required for closure of the carbon network consisting of n hexagons and C 60 is the first stable fullerene because it is the smallest possible to obey this rule. In this structure none of the pentagons make ...
Complexes with more than one fullerene ligand are illustrated by Ir 4 (CO) 3 (μ 4-CH)(PMe 3) 2 (μ-PMe) 2 (CNCH 2 Ph)(μ-η 2:η 2 C 60)(μ 4-η 1:η 1:η 2:η 2 C 60). In this Ir 4 cluster two fullerene ligands with multiple types of mixed binding. Platinum, palladium, and nickel form complexes of the type C 60 ML 2 where L is a monodentate ...
Perko is a product of three Pueblo D60 schools — Sunset Park Elementary, Pitts Middle School and Central High School. After graduating from Central in 2005, he attended the University of ...
For example, in buckminsterfullerene (C 60) this happens for the species C 60 10+, which has 50 π-electrons: 50/2 = 25, which is a perfect square. [ 1 ] In 2011, Jordi Poater and Miquel Solà expanded Hirsch's rule to open-shell spherical compounds, which have unfilled outer shells but are still aromatic.