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  2. Optical rotation - Wikipedia

    en.wikipedia.org/wiki/Optical_rotation

    The two asymmetric crystal forms, dextrorotatory and levorotatory, of tartaric acid. Sucrose solution concentration measuring experiment, demonstrating optical rotation. The rotation of the orientation of linearly polarized light was first observed in 1811 in quartz by French physicist François Arago. [8]

  3. Absolute configuration - Wikipedia

    en.wikipedia.org/wiki/Absolute_configuration

    The dextrorotatory isomer of glyceraldehyde is, in fact, the D-isomer. Nine of the nineteen L-amino acids commonly found in proteins are dextrorotatory (at a wavelength of 589 nm), and D-fructose is also referred to as levulose because it is levorotatory.

  4. Specific rotation - Wikipedia

    en.wikipedia.org/wiki/Specific_rotation

    The CRC Handbook of Chemistry and Physics defines specific rotation as: For an optically active substance, defined by [α] θ λ = α/γl, where α is the angle through which plane polarized light is rotated by a solution of mass concentration γ and path length l.

  5. Racemization - Wikipedia

    en.wikipedia.org/wiki/Racemization

    Two enantiomers of a generic amino acid that is chiral. Chiral molecules have two forms (at each point of asymmetry), which differ in their optical characteristics: The levorotatory form (the (−)-form) will rotate counter-clockwise on the plane of polarization of a beam of light, whereas the dextrorotatory form (the (+)-form) will rotate clockwise on the plane of polarization of a beam of ...

  6. Chirality (chemistry) - Wikipedia

    en.wikipedia.org/wiki/Chirality_(chemistry)

    Two enantiomers of a generic amino acid that are chiral (S)-Alanine (left) and (R)-alanine (right) in zwitterionic form at neutral pH. In chemistry, a molecule or ion is called chiral (/ ˈ k aɪ r əl /) if it cannot be superposed on its mirror image by any combination of rotations, translations, and some conformational changes.

  7. Glucose - Wikipedia

    en.wikipedia.org/wiki/Glucose

    The fact that d-glucose is dextrorotatory is a combined effect of its four chiral centres, not just of C-5; some of the other d-aldohexoses are levorotatory. The conversion between the two anomers can be observed in a polarimeter since pure α- d -glucose has a specific rotation angle of +112.2° mL/(dm·g), pure β- d -glucose of +17.5° mL ...

  8. Enantiomer - Wikipedia

    en.wikipedia.org/wiki/Enantiomer

    (S)-(+)-lactic acid (left) and (R)-(–)-lactic acid (right) are nonsuperposable mirror images of each other.. In chemistry, an enantiomer (/ɪˈnænti.əmər, ɛ-, -oʊ-/ [1] ih-NAN-tee-ə-mər), also known as an optical isomer, [2] antipode, [3] or optical antipode, [4] is one of a pair of molecular entities which are mirror images of each other and non-superposable.

  9. Monosaccharide - Wikipedia

    en.wikipedia.org/wiki/Monosaccharide

    The two stereoisomers are identified with the prefixes D - and L-, according to the sense of rotation: D-glyceraldehyde is dextrorotatory (rotates the polarization axis clockwise), while L-glyceraldehyde is levorotatory (rotates it counterclockwise). D - and L-glucose